Dehydration of aluminum chloride hexahydrate

Compositions – Compositions containing a single chemical reactant or plural... – Organic reactant

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204 67, 423DIG12, 423495, C09K 300, C01F 758

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044937849

ABSTRACT:
A method for dehydrating aluminum chloride hexahydrate which comprises contacting the hexahydrate with a melt consisting essentially of a chlorobasic mixture of aluminum chloride and alkali metal chloride and then treating the resulting mixture with HCl to form an AlCl.sub.3 /alkali metal chloride melt enriched in AlCl.sub.3. NaCl is a preferred alkali metal chloride.

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patent: 4264569 (1981-04-01), Sinha
patent: 4378337 (1983-03-01), Dunn, Jr.
Picard, G. et al., Bull. Soc. Chim. Fr., 1981, No. 9-10, Pt. 1, pp. 353-360.
Tremillon, B. et al., J. Electroanal. Chem., 74, 53-67, (Switz., 1976).
Bernard Gilbert et al., "Electrochemistry and the Behavior of Oxide Ions in Chloroaluminate Melts", J. Am. Chem. Soc., Apr. 26, 1978, pp. 2725-2730.

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