Dehydration of acetic acid by extractive distillation

Distillation: processes – separatory – Distilling to separate or remove only water – From organic compound

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203 51, 203 57, 203 58, 203 60, 203 61, 203 62, 562608, B01D 340, C07C 5144, C07C 5308

Patent

active

047298189

ABSTRACT:
Acetic acid cannot be easily removed from acetic acid--water mixtures by distillation because of the closeness of their boiling points and the deviation from ideal solution behavior. Acetic acid can be readily removed from mixtures containing it and water by using extractive distillation in which the extractive distillation agent is a mono carboxylic acid, either singly or admixed with high boiling organic compounds. Typical examples of effective agents are pelargonic acid; heptanoic acid and isophorone; neodecanoic acid, acetophenone and nitrobenzene.

REFERENCES:
patent: 1477076 (1923-12-01), Piron
patent: 1996755 (1935-04-01), Dreyfus
patent: 2041668 (1903-05-01), Wentworth
patent: 2588268 (1952-03-01), Mercer et al.
patent: 2651605 (1953-09-01), Hartley et al.
patent: 3951755 (1976-04-01), Sartorius et al.
patent: 4353784 (1982-10-01), Koga et al.

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