Degradation and detoxification of halogenated olefinic hydrocarb

Chemistry: electrical and wave energy – Processes and products

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423419R, 423500, C25B 302

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044682972

CLAIM:
providing an electrolytic cell fitted with an anode and a cathode and containing an aprotic solvent selected from the group consisting of dimethylformamide or acetonitrile adjacent the cathode, the aprotic solvent containing an electrolyte soluble therein and being substantially free of water;
adding the hydrocarbon compound to said aprotic solvent;
electrolytically generating superoxide ion at the cathode to react with the hydrocarbon compound to form a degradation product thereof, the degradation product reacting with the aprotic solvent to form chloride ion and bicarbonate; and
removing said chloride ion and bicarbonate from the electrolytic cell.

REFERENCES:
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