Communications: directive radio wave systems and devices (e.g. – Determining distance – Material level within container
Reexamination Certificate
2000-03-06
2001-07-03
Lobo, Ian J. (Department: 3662)
Communications: directive radio wave systems and devices (e.g.,
Determining distance
Material level within container
C266S094000
Reexamination Certificate
active
06255983
ABSTRACT:
TECHNICAL FIELD
This invention relates to apparatus and methods for measuring the thickness of slag on the top of a vessel of molten steel or other molten metal. An improved knowledge of the thickness of the slag, and hence its quantity, permits improved control of the amount of iron oxides and other constituents of the slag. The invention therefore includes methods and apparatus for controlling the chemistry of slag in steelmaking vessels. It also encompasses estimating the average top level of the slag, and estimating the volume above the surface of the slag which is available for additions to the vessel. In addition, it provides methods and apparatus for degassing molten steel and in particular the accurate placement of a degasser in a ladle of molten metal.
Our invention is applicable generally to the measurement of the thickness of a layer of one material on top of another material, through the use of microwave radar.
BACKGROUND OF THE INVENTION
Microwave radar has been used for years to measure the levels of various substances. The basic principle is known that the distance from the radar sender/receiver to the object under scrutiny is directly related to the time expiring between sending and receiving the radar signal, and the distance is accordingly readily computed from the elapsed time. In recent years, smaller and less expensive radar systems have become available, and their accuracy has been improved so that relatively close objects and levels of materials can be measured with confidence. The art has learned to measure or compensate for turbulence as well as unevenness in surfaces. Radar microwave is excellent for measuring a level below a layer of foam, which is otherwise hidden from view. Radar can penetrate the covers of some vessels, such as plastic lids, to determine the level of materials beneath them. The ability of contemporary computers to handle large quantities of data has also expanded the potential for radar usage.
The production of steel is historically a batch process comprising an oxidizing (or basic oxygen process) stage and a refining, or reducing stage. Generally, after the basic oxygen process, the co-produced slag floating on top of the molten steel will have a high iron oxide content and a high manganese oxide content. This slag follows the molten steel when it is poured into ladles and other vessels. The slag must be treated to reduce the iron oxide content.
If the iron oxide content of the slag is not reduced in the process of making aluminum deoxidized steel, the alumina that forms can cause caster nozzle clogging and surface defects. On the other hand, if the slag is excessively deoxidized, such that the resulting sum of iron and manganese oxides is less than 2%, then complex magnesium aluminate spinel inclusions may form. These can also cause nozzle clogging and quality defects. Furthermore, if too much slag reducing agent is added, the steel chemistry may be changed and miss the product specifications. The operators must also be aware if there is not enough free volume, or “freeboard” above the slag to accommodate the additional volume of slag treating agents to be added.
Although the concentration of iron oxide in the slag may be determined reasonably accurately, it has been difficult to determine the quantity of slag present, and many approaches have been followed to measure the thickness of the slag in order to decide how much aluminum, calcium carbide, or silicon to add to reduce the iron oxide. For example, a slag depth approximation may be computed from overall weight and the top slag level, since slag density can be determined reasonably accurately.
See Richard E. Kracich and Kenneth Goodson, “Ladle Slag Depth Measurement”, 1996 Steelmaking Conference Proceedings, 53-60. In this paper, the authors describe a slag depth measuring system including measuring the lower level of slag by a “slag/steel interface electronics” coil, a probe which must penetrate the slag layer and beyond, where the induction effects of the coil are changed by the presence of the molten steel. Other kinds of probes used in the past include simple steel bars; the bar is inserted until its extremity is melted by the molten steel, and the thickness of the slag is assumed to be the length of the red-hot portion after the bar is pulled out. But frequently the upper crust of the slag does not heat the bar enough. Any device which must penetrate the slag to measure its depth must be expected not to last very long. Moreover, slag depth varies over its area, and the single probe techniques do not account for such variations. Nevertheless, such devices can often be relied upon at least for determination of the upper level of the molten steel, which is relatively constant and can be measured reliably at a single point.
Tezuka and Nagamune, in a paper entitled “M-Sequence Modulated Microwave Level Meter and its Application” presented at the 1994 Steelmaking Conference Proceedings, 181-185, describe the measurement of the level of molten iron in a moving car, using a microwave technique; they also measure the top level of slag in a vessel. However, the microwave emissions were not shaped and accordingly a large portion of radiation received represented reflections from the sides of the vessels.
We are interested in determining not merely the upper level of the slag, but the lower level as well, so we can calculate the quantity of slag to be treated with reducing and other materials, such as aluminum or calcium carbide. It may be noted that the above mentioned Kracich and Goodson paper contains the following statement: “A microwave unit for measuring slag depth was tested, but was not feasible due to time constraints, cost and durability in the harsh environment.” Our technique has overcome these problems and many others we encountered.
In addition, we are interested in determining the thickness of various materials residing on others.
This continuation-in-part entitled “Degasser Guide” is directed to the use of radar measurements of slag levels and thickness to enable the accurate placement of a vacuum degasser in steelmaking. The most common contemporary degassing processes use a degassing chamber positioned above the ladle; the molten steel is caused by vacuum to flow into the chamber where dissolved gases, such as oxygen, hydrogen and carbon monoxide, are removed by the applied vacuum. The chamber is equipped with one or two “snorkel” tubes which are lowered to penetrate through the slag layer and the steel is either repeatedly drawn into the chamber and released or it is caused to flow up one snorkel tube and down the other. Means are provided for lowering and raising the chamber and the tube(s). But without an accurate estimate of the thickness of the slag layer, it is difficult to direct the snorkel to the most efficient depth.
Refractories in the liquid metal contact areas (the snorkels, throat and lower sidewall) are susceptible to corrosion due to reactions with the steel and slag. Refractory erosion in these areas results from the highly turbulent steel and slag washing over the refractory hot-face. Contamination of the ladle top slag must be minimized, as iron oxide (FeO) attack, resulting from the oxidation of residual steel left in the vessel after treatment can result in erosion and corrosion of refractories if temperatures are high enough to create liquid formation.
It is known to add materials such as ferrosilicon, aluminum, carbon and ferromanganese to the steel while it is being degassed.
Our invention as applied to positioning of the degassing chamber and the snorkel is also useful and in all ways compatible with the treatment of steel with additives during degassing.
SUMMARY OF THE INVENTION
Radar reflectance is highly dependent on the conductivity and, to an extent, the dielectric constant of the material or surface to be contacted or measured. Highly conductive subjects, such as acids and graphite, reflect microwaves very well, more or less independently of the dielectric constant so that these materials can be measured with few problems. Generally
Kemeny Frank L.
Mannion Frederick J.
Meszaros Gregory A.
Walker David J.
Zaranek Richard J.
Krayer William L.
Lobo Ian J.
USX Corp
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