Defluorination of alkane streams

Chemistry of hydrocarbon compounds – Purification – separation – or recovery – By addition of extraneous agent – e.g. – solvent – etc.

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585856, 585733, C07C 700, C07C 717, C07C 100

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active

053960220

ABSTRACT:
An alkane/fluoroalkane feed is treated with an acidic alumina to reduce the amount of fluoroalkane(s) in the feed. In a particularly preferred embodiment, the feed is treated with a sulfur-containing alumina so as to convert a major portion of fluoroalkane(s) to higher alkane(s).

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Kozo Tanabe, "Solid Acids and Bases", 1970, Academic Press, pp. 45-50.
Herman Pines et al., "Alumina: Catalyst and Support . . . ", Journal of the American Chemical Society 82 (1960), pp. 2471-2483.

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