Deeply reduced oxidation catalyst and its use in preparing...

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus acids or salts thereof

Reexamination Certificate

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C502S174000, C502S180000, C502S182000, C502S183000, C502S184000

Reexamination Certificate

active

07067693

ABSTRACT:
This invention relates to an improved catalyst, comprising a carbon support having a noble metal at its surface, for use in catalyzing liquid phase oxidation reactions, especially in an acidic oxidative environment and in the presence of solvents, reactants, intermediates, or products which solubilize noble metals; a process for the preparation of the improved catalyst; a liquid phase oxidation process using such a catalyst wherein the catalyst exhibits improved resistance to noble metal leaching, particularly in acidic oxidative environments and in the presence of solvents, reactants, intermediates, or products which solubilize noble metals; and a liquid phase oxidation process in which N-(phosphonomethyl)iminodiacetic acid (i.e., “PMIDA”) or a salt thereof is oxidized to form N-(phosphonomethyl) glycine (i.e., “glyphosate”) or a salt thereof using such a catalyst wherein the oxidation of the formaldehyde and formic acid by-products into carbon dioxide and water is increased.

REFERENCES:
patent: 3340097 (1967-09-01), Hess et al.
patent: 3799758 (1974-03-01), Franz
patent: 3835000 (1974-09-01), Frazier et al.
patent: 3927080 (1975-12-01), Gaetner
patent: 3950402 (1976-04-01), Franz
patent: 3954848 (1976-05-01), Franz
patent: 3956370 (1976-05-01), Parry et al.
patent: 3969398 (1976-07-01), Hershman
patent: 4026950 (1977-05-01), Le Ludec
patent: 4147719 (1979-04-01), Franz
patent: 4186110 (1980-01-01), Jalan et al.
patent: 4190605 (1980-02-01), Muench et al.
patent: 4264776 (1981-04-01), Hershman et al.
patent: 4415479 (1983-11-01), Puskas et al.
patent: 4507250 (1985-03-01), Bakel
patent: 4525294 (1985-06-01), Sartori et al.
patent: 4582650 (1986-04-01), Felthouse
patent: 4624937 (1986-11-01), Chou
patent: 4654429 (1987-03-01), Balthazor et al.
patent: 4696772 (1987-09-01), Chou
patent: 4775498 (1988-10-01), Gentilcore
patent: 4810426 (1989-03-01), Fields, Jr. et al.
patent: 4851131 (1989-07-01), Grabiak et al.
patent: 4921991 (1990-05-01), Lacroix
patent: 4970128 (1990-11-01), Itoh et al.
patent: 4978649 (1990-12-01), Surovikin et al.
patent: 5023369 (1991-06-01), Fields, Jr.
patent: 5024905 (1991-06-01), Itoh et al.
patent: 5077431 (1991-12-01), Fields, Jr.
patent: 5079107 (1992-01-01), Jalan
patent: 5087740 (1992-02-01), Smith
patent: 5091561 (1992-02-01), Riley et al.
patent: 5095140 (1992-03-01), Fields, Jr.
patent: 5096866 (1992-03-01), Itoh et al.
patent: 5178971 (1993-01-01), Itoh et al.
patent: 5179228 (1993-01-01), Martin Ramon et al.
patent: 5189005 (1993-02-01), Watanabe et al.
patent: 5225391 (1993-07-01), Stonehart et al.
patent: 5292936 (1994-03-01), Franczyk
patent: 5356849 (1994-10-01), Matviya et al.
patent: 5367112 (1994-11-01), Franczyk
patent: 5410085 (1995-04-01), Birkenstock et al.
patent: 5500485 (1996-03-01), Hodgkinson
patent: 5585083 (1996-12-01), Kielin et al.
patent: 5602276 (1997-02-01), Stern et al.
patent: 5606107 (1997-02-01), Smith
patent: 5627125 (1997-05-01), Ebner et al.
patent: 5658839 (1997-08-01), de Agudelo et al.
patent: 5688994 (1997-11-01), Baysdon et al.
patent: 5759944 (1998-06-01), Buchanan et al.
patent: 5876867 (1999-03-01), Itoh et al.
patent: 5882619 (1999-03-01), Heineke et al.
patent: 6005140 (1999-12-01), Morgenstern et al.
patent: 6153753 (2000-11-01), Johnson et al.
patent: 58285/80 (1980-11-01), None
patent: 0019445 (1980-11-01), None
patent: 0019445 (1980-11-01), None
patent: 0 055 695 (1982-07-01), None
patent: 0 162 035 (1985-11-01), None
patent: 0 408 528 (1991-01-01), None
patent: 0 595 124 (1994-05-01), None
patent: 0 680 948 (1995-11-01), None
patent: 0 081 978 (1997-10-01), None
patent: 1 601 715 (1981-11-01), None
patent: WO 96/19485 (1996-07-01), None
patent: WO 98/35930 (1998-08-01), None
patent: WO 99/41260 (1999-08-01), None
patent: WO/00/01707 (2000-01-01), None
Affidavit of Thomas J. Richard, dated Jul. 16, 1985, filed Aug. 14, 1985 in the Australian Patent Office in connection with the Opposition of Australian Application No. 58285/80 (Acceptance No. 542716) by Monsanto Company, including Exhibits TJR-1 through TJR-7.
Declaration of Dr. Peter Hajdu, dated May 28, 1986, filed in the Australian Patent Office in connection with the Opposition of Australian Application No. 58285/80 (Acceptance No. 542716) by Monsanto Company, including Exhibits PH1 through PH5.
Jul. 9, 1999 PCT Search Report in Application PCT/US99/03402, Filed Feb. 17, 1999 (which corresponds to this application).
Andrew, M.R. et al., “The Characterization of Pt/Sn Catalyst For The Electrochemical Oxidation Of Methanol”,Journal Of Applied Electrochemistry, 6, pp. 99-106, 1976.
Aricò, A.S. et al., “Methanol Oxidation On Carbon-Supported Pt-Sn Electrodes In Silicotungstic Acid”,Electrochimica Acta.,vol. 39, No. 5, pp. 691-700, 1994.
Balakrishnan, K. et al., “A Chemisorption And XPS Study Of Bimetallic Pt-Sn/Al2O3Catalysts”,Journal of Catalysis 127, pp. 287-306, 1991.
Burch, R., “The Oxidation State Of Tin And The Interaction Between Platinum And Tin”,Journal of Catalysis, pp. 348-359, 1981.
Cameron, D.S. et al., “Carbons As Supports For Precious Metal Catalysts”,Catalysis Today, vol. 7, pp. 113-137, 1990.
Campbell, S. et al., “Effect Of Bi And Sn Adatoms On Formic Acid And Methanol Oxidation At Well Defined Platinum Surfaces”,Journal of Chemical Society, Faraday Trans., vol. 88, No. 6, pp. 833-841, 1992.
Cathro, K.J., “The Oxidation Of Water-Soluble Organic Fuels Using Platinum-Tin Catalysts”,J. Electrochem. Soc.: Electrochemical Technology, vol. 116, No. 11, pp. 1608-1611, 1969.
Coloma, F. et al., “Heat-Treated Carbon Blacks As Supports For Platinum Catalysts”,Journal of Catalysis 154, pp. 299-305, 1995.
Coloma, F. et al., “Preparation Of Platinum Supported On Pregraphitized Carbon Blacks”,Langmuir, 10, pp. 750-755, 1994.
Dubinin, M.M., “Microporous Structures Of Carbonaceous Adsorbents”,Carbon, vol. 20, No. 3, pp. 195-200, 1982.
Franklin, T. et al., “The Effect Of Anionic Poisons On the Catalytic Oxidation Of Formaldehyde On Platinum”,Journal of Catalysis 42, pp. 360-366, 1976.
Gallezot, P. et al., “Catalytic Oxidations With Air For Clean And Selective Transformations Of Polyols”,Catalysis Of Organic Reactions, pp. 331-340, (Scaros et al., eds. Marcel Dekker, Inc., New York, NY,1994).
Gökaǵac, G. et al., “Characterisation Of Carbon-Supported Pt-Sn Bimetallic Catalysts for The Electrochemical Oxidation Of Methanol”,Journal of Chemical. Society, Faraday Trans., vol. 89, No. 1, pp. 151-157, 1993.
Kim, T.K. et al., “Preparation Of Carbon-Supported Platinum Catalysts: Adsorption Mechanism of Anionic Platinum Precursor Onto Carbon Support”,Carbon, vol. 30, No. 3, pp. 467-475, 1992.
Kimura, H. et al., “Palladium Based Multi-Component Catalytic Systems For the Alcohol To Carboxylate Oxidation Reaction”,Applied Catalysis A: General, vol. 95, pp. 143-169, 1993.
Kimura, H., “Selective Oxidation Of Glycerol On A Platinum-bismuth Catalyst By Using A Fixed Bed Reactor”,Applied Catalysis A: General, vol. 105, pp. 147-158, 1993.
Luk'yanova, Z.V. et al., “Determination Of the Surface Area Of Platinum In Adsorption Catalysts From The Amount Of ‘Soluble’ Platinum”,Russian Journal of Physical Chemistry, vol. 53, No. 2, pp. 225-227, 1979.
Maier, L., “Organic Phosphorus Compounds 95. A Simple Method For The Preparation Of N-Dihydroxyphosphonylmethyl-Glycine (Glyphosate)”,Phosphorus, Sulfur, and Silicon, vol. 61, pp. 65-67, 1991.
Mallat, T. et al., “Preparation Of Promoted Platinum Catalysts Of Designed Geometry And The Role Of Promoters In The Liquid-Phase Oxidation of 1-Methoxy-2-Propanol”,Journal Of Catalysis 142, pp. 237-253, 1993.
Margitfalvi, J. et al., “Supported Bimetallic Catalysts Prepared By Controlled Surface Reactions”, ch.11, pp. 373-409.
Merlen, E. et al., “Characterization Of Bimetallic Pt-Sn/A12O3Catalysts: R

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