Decyl alcohol mixtures, phthalic esters obtainable therefrom and

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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560 76, 568452, 568453, 568882, 568883, C08K 509, C07C 6976

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active

054629861

ABSTRACT:
Mixtures of isomeric decyl alcohols prepared by hydroformylation of mixtures of butene-1 and butene-2 in two stages to give aldehyde mixtures, and condensation of the aldehyde mixtures to form an aldol mixture, followed by separation and hydrogenation. The first stage of the hydroformylation proceeds in the presence of rhodium catalysts dissolved in water, the second stage in the presence of cobalt catalysts homogeneously dissolved in the reaction medium. The mixture of isomeric decyl alcohols, when esterified with phthalic acid, yields a mixture of isomeric decyl phthalates which are useful as plasticizers.

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patent: 4684750 (1987-08-01), Kessen et al.
patent: 5189105 (1993-02-01), Miyazawa et al.
patent: 5268514 (1993-12-01), Bahrmann et al.
patent: 5369162 (1994-11-01), Bahrmann et al.

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