Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...
Reexamination Certificate
2001-03-13
2003-02-04
Sanders, Kriellion A. (Department: 1714)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
At least one aryl ring which is part of a fused or bridged...
C524S044000, C524S317000, C524S386000, C524S432000, C524S437000, C524S492000
Reexamination Certificate
active
06515062
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The instant invention relates generally to construction materials, and more particularly to stucco coating compositions and methods for preparing same.
2. Description of Related Art
Aluminum metal pigments are widely used in the coating industry to produce finishes of the type which have a metallic luster. Because pure dry aluminum metal pigments are explosive, and consequently difficult to store, they are usually supplied in stabilized form as pastes or dispersions wherein the aluminum particles are stabilized by resinous carriers or solvents. The procedure generally used to produce a colored finish with a metallic luster involves dispersing both a metallic pigment and a transparent colored pigment in a suitable vehicle. A stabilized aluminum pigment suitable for use in such a process is described in U.S. Pat. No. 5,773,492. Alternatively, colored aluminum pigments can be prepared by coating aluminum particles with a polymer matrix encapsulating a solid colorant cured thereon, and incorporating them into a dispersion. Such pigments are described in U.S. Pat. No. 5,814,686. Although the dispersions in U.S. Pat. Nos. 5,773,492 and 5,814,686 are disclosed as having utility for imparting metallic luster and color to surface coatings, their use in stucco is not taught. These dispersions have achieved wide acceptance as metallic aluminum paints, primarily in the automotive industry wherein a finish with a metallic luster is desired. A critical attribute of the aluminum metal pigment for such utilities is its fine mesh. Coarse grade aluminum metal pigments are not suitable for such uses.
A variety of synthetic stucco compositions are known in the art, each of which attempts to solve one or more problems associated with the use of conventional natural stucco materials which have been use for hundreds of years. U.S. Pat. No. 4,351,912, for example, is directed to a trowelable, light-weight, synthetic stucco composition containing a crushable, lightweight aggregate, and specifically to the protection of the lightweight aggregate from substantial particle size reduction during trowelling application by providing in the composition a non-crushable aggregate having a protective particle size. U.S. Pat. No. 4,563,491 provides a synthetic stucco which incorporates baking flour which purports to be effective against variety of adverse environmental influences, including ultraviolet radiation, humidity, salt spray, fire and thermal effects. Examples such as these illustrate the fact that the precise blend of ingredients required to produce desired attributes in a new synthetic stucco are difficult to predict, and that considerable trial and error are involved in creating a new stucco composition.
A successful new synthetic stucco must be able to “breathe” to avoid problems with blistering and condensation. The present invention provides decorative synthetic stucco compositions having a shiny sparkling metallic finish, and methods for making same. Beneficially it has been found that the use of stabilized coarse mesh aluminum metal pigment in said compositions along with the metal carrier bentonite produces synthetic stucco compositions which are able to breathe, and which have an aesthetically pleasing shiny sparkling metallic finish.
SUMMARY OF THE INVENTION
In brief, the present invention provides decorative synthetic stucco compositions having a shiny sparkling metallic finish comprising 75-100 parts by weight of a synthetic stucco finish coating and 1 part by weight of approximately 200 mesh stabilized aluminum metal pigment. Also provided are such compositions further comprising 1-20 parts per thousand by weight of a metallic pigment for coloring said compositions. Finally, the present invention also provides methods for making synthetic stucco compositions having a shiny, sparkling metallic finish.
DETAILED DESCRIPTION OF THE INVENTION
The preferred embodiment of the present invention is one wherein the synthetic stucco finish coating and the stabilized aluminum metal pigment are present in the ratio of 85-90:1, and said stabilized aluminum metal pigment is Silberline AQUASIL® BP 2750 aluminum pigment available from Silberline Manufacturing Company, Inc.
This invention also provides synthetic stucco compositions having a shiny sparkling metallic finish further comprising colored metal pigments. Metal pigments can be added, in such quantities as required to give the composition the desired color. Preferred pigments of the present invention are metal-based, more preferably belonging to the iron oxide class. Compositions having 1-20 parts per thousand by weight of one or more iron oxide based pigments are most preferred.
The synthetic stucco finish coating of the present invention can contain mineral carriers, binders, fillers, acrylic resins, and various additives such as dispersants, defoamers, coalesing agents, rheology modifiers, white pigments, preservatives such as fungicides, solvents as needed to obtain a fluid combination, and aqueous ammonia as needed to adjust the pH to 7.0-8.8.
Mineral carriers suitable for use in the compositions of this invention include, but are not limited to, bentonites such as calcium bentonite and sodium bentonite; montmorillonite clays; kaolin clays; diatomaceous earth; and talc; and mixtures thereof. Sodium bentonite is a preferred mineral carrier.
Binders suitable for use in the compositions of the present invention include, but are not limited to, cellulose based binders such as sodium carboyxymethyl cellulose, hydroxy methyl cellulose, methyl cellulose, ethyl cellulose, and the like; dextrin; starch; poly(vinyl alcohol); sodium alginate; sodium polyacrylate; and gums such as xanthan gum, welan gum, gum arabic and the like; and mixtures thereof. Ethyl hydroxyethyl cellulose is a preferred binder.
Fillers of use in the present invention include silica, volcanic sand, and ground marble. A preferred filler is silica. More preferred is silica having a mesh size substantially in the range of 35-200 mesh.
Acrylic resins of use in the present invention are acrylic latexes including polymers and copolymers containing units of acrylic acid, methacrylic acid, their esters, acrylonitrile, and styrene. A preferred acrylic resin of the present invention is a styrene/acrylate copolymer dispersion.
A variety of dispersants of use in the present invention are known in the art, and are commercially available. The preferred dispersant is maleic anhydride-isobutylene polymer sodium salt.
The preferred defoamer of use in the present invention is NOPCO®, a trade secret blend available from Henkel Corporation.
A variety of coalescing agents of use in the present invention are known in the art, and are commercially available. The preferred coalescent is coalescent 2,2,4-trimethyl-1,3-pentanediol momo(2-propionate).
Rheology modifiers of use in the present invention are acrylic resin based. The preferred rheolgy modifier is PolyPhobe® 111 available from Union Carbide.
White pigments suitable for use in the compositions of the present invention are zinc oxide and zinc sulfide. Zinc oxide is a preferred white pigment since it adventitiously also functions as a fungicide.
The preferred embodiment of the synthetic stucco finish coating of the present invention comprises on a weight basis the binder ethyl hydroxyethyl cellulose, substantially in the range of 1.0-2.5 parts; the solvent propylene glycol, substantially in the range of 10-12 parts; the dispersant maleic anhydride-diisobutylene polymer sodium salt, substantially in the range of 1-3 parts; the defoamer NOPCO®, substantially in the range of 0.5-1.5 parts; the coalescent 2,2,4-trimethyl-1,3-pentanediol mono(2-propionate), substantially in the range of 2-4 parts; the rheology modifier PolyPhobe® 111, substantially in the range of 1-2 parts; the mineral carrier sodium bentonite, substantially in the range of 7-9 parts; the filler silica having a particle size of 200 mesh, substantially in the range of 5-7 parts; the white pigment/fungicide zinc oxide substantially in t
Icote USA, Inc.
Manero Charles
Sanders Kriellion A.
Woodbridge Richard C.
Woodbridge & Associates P.C.
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