Decorative corrosion and abrasion resistant coating

Stock material or miscellaneous articles – Composite – Of metal

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C428S469000, C428S697000, C428S698000, C428S701000, C428S702000, C428S627000

Reexamination Certificate

active

06245435

ABSTRACT:

THE FIELD OF THE INVENTION
The present invention relates to decorative coatings for articles of manufacture such as faucets and related plumbing products including shower heads, escutcheons, tub spouts and the like. More specifically, the invention concerns a decorative coating for such a product, which is resistant to corrosion, abrasion and attack by chemicals, and has a specified decorative color other than brass. The invention is particularly concerned with such a decorative coating which resists corrosion, a common problem in many present-day decorative coatings, and uses only zirconium or hafnium as the principal component of the outer decorative layer. There are numerous prior art patents which disclose the use of zirconium to provide a corrosion resistant brass appearing decorative outer coating. However, attempts to apply the principles of such prior art disclosures to provide colors other than brass, through use of principal components for the outer coating other than zirconium or hafnium, have all resulted in failure. The present invention provides such a coating in which the color is other than brass, for example gray, gold or black, but uses zirconium or hafnium as the principal component of the outer layer, with the parameters of the physical vapor deposition process (PVD) being manipulated to provide an outer layer which has the desired resistance to corrosion, abrasion and attack from chemicals.
SUMMARY OF THE INVENTION
The present invention relates to articles of manufacture with a decorative coating other than brass and more specifically to such a coating which is resistant to corrosion, abrasion and attack by chemicals.
A primary purpose of the invention is to provide a new article of manufacture which has a specified decorative color, for example gray, gold or black, and includes an outer layer which has as a principal component only zirconium or hafnium.
Another purpose is an article of manufacture of the type described in which the outer layer applied by physical vapor deposition can provide different colors, depending upon the specific parameters of the deposition process, through the use of only zirconium or hafnium as the principal component of the outer layer.
Another purpose is an article of manufacture of the type described in which the substrate is essentially free of surface flaws and porosity and is chosen from the group comprising brass, a metal glass and zinc castings produced by a semi-solid or slush casting process.
Another purpose is a corrosion resistant article of manufacture of the type described, for example door hardware, or a faucet or related plumbing component, having enhanced corrosion resistance by the maintenance of a passivating layer on the exterior thereof.
Other purposes will appear in the ensuing specification, drawing and claims.


REFERENCES:
patent: Re. 33530 (1991-02-01), Munz et al.
patent: 3958070 (1976-05-01), Schintlmeister et al.
patent: 4209552 (1980-06-01), Welch
patent: 4219199 (1980-08-01), Okuda
patent: 4296178 (1981-10-01), Griesenauer et al.
patent: 4351855 (1982-09-01), Pinkhasov
patent: 4369225 (1983-01-01), Manabe et al.
patent: 4395313 (1983-07-01), Lindsay et al.
patent: 4402998 (1983-09-01), Kumagai et al.
patent: 4407998 (1983-10-01), Duvdevani
patent: 4415421 (1983-11-01), Sasanuma
patent: 4420498 (1983-12-01), Hirose et al.
patent: 4426267 (1984-01-01), Munz et al.
patent: 4431711 (1984-02-01), Eisfeller
patent: 4438153 (1984-03-01), Pinkhasov
patent: 4447473 (1984-05-01), Mashida et al.
patent: 4466872 (1984-08-01), Einbinder
patent: 4470895 (1984-09-01), Coad et al.
patent: 4517217 (1985-05-01), Hoffman
patent: 4524106 (1985-06-01), Flasck
patent: 4544468 (1985-10-01), Munz et al.
patent: 4582564 (1986-04-01), Shanefield et al.
patent: 4590031 (1986-05-01), Eichen et al.
patent: 4591418 (1986-05-01), Snyder
patent: 4603057 (1986-07-01), Ueno et al.
patent: 4604168 (1986-08-01), Liu et al.
patent: 4606941 (1986-08-01), Jenkin
patent: 4612216 (1986-09-01), Kurfman
patent: 4620913 (1986-11-01), Bergman
patent: 4629662 (1986-12-01), Brownlow et al.
patent: 4713150 (1987-12-01), Hornbostel et al.
patent: 4716083 (1987-12-01), Eichen et al.
patent: 4737252 (1988-04-01), Hoffman
patent: 4763601 (1988-08-01), Saida et al.
patent: 4824540 (1989-04-01), Stuart
patent: 4842945 (1989-06-01), Ito et al.
patent: 4849082 (1989-07-01), Baty et al.
patent: 4876119 (1989-10-01), Takeda et al.
patent: 4882022 (1989-11-01), Hoffman et al.
patent: 4895630 (1990-01-01), Aufderheide
patent: 4900630 (1990-02-01), Suzuki et al.
patent: 4911811 (1990-03-01), Mullaney, Jr.
patent: 4919773 (1990-04-01), Naik
patent: 4937094 (1990-06-01), Doehler et al.
patent: 4950365 (1990-08-01), Evans
patent: 4973388 (1990-11-01), Francois et al.
patent: 5015308 (1991-05-01), Yamagata
patent: 5022978 (1991-06-01), Hensel et al.
patent: 5055318 (1991-10-01), Deutchman et al.
patent: 5091209 (1992-02-01), Claverie et al.
patent: 5126030 (1992-06-01), Tamagaki et al.
patent: 5234560 (1993-08-01), Kadlec et al.
patent: 5234561 (1993-08-01), Randhawa et al.
patent: 5366764 (1994-11-01), Sunthankar
patent: 5374451 (1994-12-01), Servais et al.
patent: 5407548 (1995-04-01), Kopacz et al.
patent: 5413874 (1995-05-01), Moysan, III et al.
patent: 5429070 (1995-07-01), Campbell et al.
patent: 5447803 (1995-09-01), Nagaoka et al.
patent: 5458754 (1995-10-01), Sathrum et al.
patent: 5458928 (1995-10-01), Kiyama et al.
patent: 5476724 (1995-12-01), Moysan, III et al.
patent: 5478659 (1995-12-01), Moysan, III et al.
patent: 5478660 (1995-12-01), Moysan, III et al.
patent: 5482788 (1996-01-01), Moysan, III et al.
patent: 5484663 (1996-01-01), Moysan, III et al.
patent: 5492725 (1996-02-01), Gordon
patent: 5510012 (1996-04-01), Schulz et al.
patent: 5512164 (1996-04-01), Timberlake
patent: 5543183 (1996-08-01), Streckert et al.
patent: 5552233 (1996-09-01), Moysan, III et al.
patent: 5624486 (1997-04-01), Schmid et al.
patent: 5626972 (1997-05-01), Moysan, III et al.
patent: 5639564 (1997-06-01), Moysan, III et al.
patent: 5641579 (1997-06-01), Moysan, III et al.
patent: 5648179 (1997-07-01), Moysan, III et al.
patent: 5654108 (1997-08-01), Moysan, III et al.
patent: 5667904 (1997-09-01), Moysan, III et al.
patent: 5683756 (1997-11-01), Tanner et al.
patent: 5693427 (1997-12-01), Moysan, III et al.
patent: 5705230 (1998-01-01), Matanabe et al.
patent: 5716721 (1998-02-01), Moysan, III et al.
patent: 5720821 (1998-02-01), Halpern
patent: 5752395 (1998-05-01), Nakamura
patent: 5759677 (1998-06-01), Fink
patent: 5773154 (1998-06-01), Takada
patent: 5783313 (1998-07-01), Moysan, III et al.
patent: 5788823 (1998-08-01), Warnes et al.
patent: 5798148 (1998-08-01), Thomas et al.
patent: 5814415 (1998-09-01), Moysan, III et al.
patent: 5858181 (1999-01-01), Jindal et al.
patent: 5879532 (1999-03-01), Foster et al.
patent: 5891556 (1999-04-01), Anderson et al.
patent: 5897753 (1999-04-01), Schatz et al.
patent: 5976634 (1999-11-01), Tanner et al.
patent: 0 353 060 (1990-01-01), None
patent: 0 430 874 A1 (1991-06-01), None
patent: 2 173 218 (1986-10-01), None
patent: 3-240942 (1991-10-01), None
Schulz, S. “Decorative Coating with Physical Coating Processes,” Leybold AG Technical Pubn. 11-S36.02, Hanau, Germany (no date).
Schulz, S., “New Directions in Decorative Hard Coatings,” Leybold AG Technical Pubn. 11-S37.02 presented at Deco-Symposium Japan, Kyoto, Japan, Jul. 12, 1990, Hanau, Germany.
Schulz, S., “What You Ever Wanted to Know About Deco Coatings,” Leybold AG Newsletter, Alzenau, Germany, Feb. 1991.
Brown, Richard, and Alias, Mohd. N., “Oxidation of Nitride Films in Aqueous Solution: Correlation Between Surface Surface Analysis and Electrochemical Studies,” University of Rhode Island Paper No. 322, presented at the Annual Conference and Corrosion Show, 1994 (no month).
Van Leaven, L., Alias, M. N. and Brown, R., “Corrosion Behavior of Ion Plated and Implanted Films,” Surface and Coatings Technology, 53 (1992) pp. 25-34 (no month).
Ristolainin, E.O., Molarius, J.M., Korhonen, A.S., and Lindroos, V.K., “A Study of Nitrogen-rich Titanium and Zirconium Nitride Fil

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Decorative corrosion and abrasion resistant coating does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Decorative corrosion and abrasion resistant coating, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Decorative corrosion and abrasion resistant coating will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2450768

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.