Plastic and nonmetallic article shaping or treating: processes – With printing or coating of workpiece – Applying indicia or design
Reexamination Certificate
2000-07-21
2003-09-23
Lee, Edmund H. (Department: 1732)
Plastic and nonmetallic article shaping or treating: processes
With printing or coating of workpiece
Applying indicia or design
C264S135000, C264S250000, C264S267000, C264S275000, C425S127000, C425S129100
Reexamination Certificate
active
06623677
ABSTRACT:
FIELD OF THE INVENTION
The invention concerns a method of manufacturing a decorated article of thermoplastic composition, more particularly, the method entails film insert molding.
SUMMARY OF THE INVENTION
A process for making a decorated article is described. The process entails printing, using a high temperature ink, a design on a surface of transfer paper, and transferring the design by sublimation to the surface of a clear flat substrate to obtain a decorated substrate. The thus decorated surface is then placed in a mold and thermoplastic resin is injected to form an article. The placing of the decorated substrate in the mold is such that the surface carrying the design faces the inside of the mold. An additional embodiment entails forming the decorated substrate to attain a three dimensional decorated substrate prior to placing it in the mold.
BACKGROUND OF THE INVENTION
Methods for preparing thermoplastically molded articles that carry decorative designs are known. Such articles are known to be prepared by injecting a thermoplastics molding composition into a mold. The decorative design is applied to a surface of the article by any of the well-known silk screening or flexographic printing techniques. Articles thus made often lose the decorative design upon friction, or have their aesthetic appeal diminished by scratches, which are encountered upon use.
Products of the general type entailed in the present invention have been made for many years by a method known in the art as an in-mold decorating process, or film-insert molding. This process, in use about thirty years, has been employed in the production of prints on resinous sheets that were used in the course of injection molding to form finished products. In this prior art process, the overlays or in-mold decorative sheets were produced by offset printing and/or by screen-printing, and the parts were. flat and were held fast into the mold by means such as static charge. This process was characterized in that it required special gating design and in that it limited the freedom of the printed design since the introduction of the plastic needed to be limited to areas where there was no ink; the interaction between design and ink would tend to move or distort the graphics.
The art is noted to include U.S. Pat. No. 2,811,744, that described a method that avoids some of the drawbacks of the prior art. Accordingly, the method thus described entails injecting the thermoplastics composition directly onto a sheet of paper that carries the decorative design that is printed with a transferable ink, the paper having been positioned in the injection mold. This ink is capable of being separated from the paper under the thermal conditions that prevail in the course of injection molding. In the course of injection, the transferable ink separates from the paper and adheres to the molded thermoplastic composition, resulting in a surface-decorated article. This method is deficient in that articles thus decorated often feature deformed or destroyed decorations. This deficiency is a result of having the molten composition move against the paper in the course of injection.
A further method of manufacturing a decorated article by injection molding was disclosed in U.S. Pat. No. 4,931,248. This method entails printing a design onto a surface of a support, the printing made using a transferable ink. The ink is characterized in that it may be separable from the support in response to heating. The printed support is introduced into a mold and a separate film is then also introduced into the mold in a position to be applied against the printed surface of the support. After introducing the support and the film, a thermoplastic material is injected into the mold. The introduction of the support is such that at least during the injection (i) the support is applied against a wall of the mold with the printed surface turned facing the inside of the mold and (ii) introduction of the film is carried out so that one surface of the film is applied against the printed surface of the support and the other surface of the film bonds itself to the thermoplastics material. The transferable ink is separating from the support and is deposited on the film under the thermal conditions prevailing in the course of injection of the molten resin.
A method of making applique products of the type made of synthetic resins and having printing thereon has been disclosed in U.S. Pat. No. 5,264,172. The method entails printing on the surface of a substrate of synthetic resin, using a formable ink, and placing the substrate in a mold cavity in a secure position with the front surface of the substrate in contact with the surface of the mold and injecting a molten resin into the cavity space. Also relevant is the method of in-mold decorating process disclosed in U.S. Pat. No. 4,917,927, the method entails a novel printing step.
DETAILED DESCRIPTION OF THE INVENTION
In accordance with the present invention, there is provided a method for making a decorated thermoplastically molded article. The method yields articles wherein the decorative design loses none of its sharpness after time in service.
The method entails printing a design or legend (herein “design”) that is intended to decorate the molded object onto one surface of a transfer paper using a high temperature transferable ink. Such printing, as well as the transfer paper and high temperature transferable ink are known. Briefly, however, the suitable transfer paper is available in commerce under the generic name of photo quality ink-jet paper. As an example of such suitable transfer paper, mention is made of AccuPlot EPQ 8511C, a product of Mile High Engineering which was found to be very suitable. Printing of the decoration or the legend may be carried out by any of the known techniques, including screen-printing and flexographic printing. In a particularly preferred embodiment, the decorative design or legend may be printed digitally. In this preferred embodiment, the resolution of the print is preferably no lower than 1440×720 dpi (dots per inch). Such resolution is attained by using, for instance, Epson Stylus Color 3000 printer. The high temperature ink, suitable in the context of the present invention is characterized in that it is capable of being sublimated and in that it remains virtually free of thermal degradation under the conditions prevailing in the injection molding process. Such suitable high temperature ink is available in commerce under the trademark Sublijet from Sawgrass.
The thus, decorated transfer paper is then, in a subsequent step of the inventive process, positioned with the legend side facing a plastic substrate, and sufficient heat, optionally along with pressure, is applied to cause sublimation of the ink and transfer of the design to the plastic substrate.
A plastic substrate in the context of the present invention is preferably in the form of a film having a thickness of 0.0035″ to 0.040″; the plastic substrate preferably comprises transparent and/or clear resin. Included among the suitable resins making up the substrate are any of polycarbonate homopolymers, copolycarbonates, acrylonitrile-butadiene-styrene resins (ABS), styrene/acrylonitrile (SAN), polyamides, thermoplastic polyurethane, as well as blends of polycarbonate, including blends with ABS. Thermoplastic compositions containing acrylic resins and polycarbonate resins are preferred. In a preferred embodiment, the substrate is in the form of a laminate containing at least two layers. In such an embodiment, one of the layers is PVF (poly vinyl fluoride) or PVDF (poly vinylidine fluoride).
The substrate that now carries the printed decoration, or legend, may be placed in an injection molding mold in its flat unshaped form or, in the alternative, be formed into a three dimensional shape that replicates the inner surface of the injection mold, trimmed to eliminate excess material, and then placed in the mold. The walls of the mold define, when the mold is closed, a cavity having the shape and dimensions of the article t
Dougherty Diane D.
Griffin Patrick J.
Heffley Keith R.
Smith Stephen G.
Bayer Corporation
Franks James R.
Gil Joseph C.
Lee Edmund H.
Preis Aron
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