Decomposition of organic hydroperoxides with nitrated porphyrin

Details Decomposition of organic hydroperoxides with nitrated porphyrin Decomposition of organic hydroperoxides with nitrated porphyrin

1993-06-09

1994-09-06

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568815, C07C 2948, C07C 3100, C07C 3300

Patent

active

053450086

ABSTRACT:
Hydroperoxides are decomposed by contact with metalloporphyrin coordination complex catalysts in which hydrogen in the porphyrin molecule has been substituted with at least one nitro group and may be further substituted with other electron-withdrawing elements or groups, for example, halogen or halocarbons, or with hydrocarbon groups. Preferred catalysts are iron tetranitro-.beta.-octaethylporphyrins and iron tetrakispentafluorophenyl-.beta.-nitroporphyrins.

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