Dechlorination of TCE with palladized iron

Liquid purification or separation – With means to add treating material

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210205, 210209, C02F 170

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active

057593892

ABSTRACT:
The present invention relates to various methods, such as an above-ground method and an in-ground method, of using a palladized iron bimetallic system for the dechlorination of chlorinated organic compounds from effluents containing the same. The use of palladized iron bimetallic system results in the dechlorination of the chlorinated organic compound into environmentally safe reaction products. The present invention also provides kits, devices, and other instruments that use the above-mentioned palladized iron bimetallic system for the dechlorination of chlorinated organic compounds.

REFERENCES:
patent: 4389311 (1983-06-01), La Freniere
Agrawal, et al., "Abiotic Remediation of Nitro-Aromatic Groundwater Contaminants by Zero-Valent Iron", American Chemical Society Abstract, Division of Environmental Chemistry, pp. 492-494, (1994).
Matheson, et al., "Abiotic and Biotic Aspects of Reductive Dechlorination of Chlorinated Solvents by Zero-Valent Iron", American Chemical Society Abstract, Division of Environmental Chemistry, pp. 414-415, (1994).
Matheson, et al., "Process Affecting Reductive Dechlorination of Chlorinated Solvents by Zero-Valent Iron", Americna Chemical Society Abstract, Division of Environmental Chemistry, pp. 3-4, (1993).
Schrier, et al., "Transformation of Tetrachloroethylene by Iron Powder", American Chemical Society Abstract, Division of Environmental Chemistry, p. 52, (1993).
O'Hannesin, et al., "In Situ Degradation of Halogenated Organics by Permeable Reaction Wall", EPA Ground Water Currents, pp. 1-2, (Mar. 1993).
Hassan, et al., "Reduction of Halogenated Hydrocarbons with Iron: II. Mechanism of the Reaction.", American Chemical Society Abstract, Division of Environmental Chemistry, pp. 8-9, (1993).
Boyes, et al., "Supported Metal Catalysts for CFC Hydrodehalogenation", American Chemistry Society, Division of Petroleum Chemistry, pp. 847-849, (1993).
Mathe, et al., "Active Environment Protection: Hydrodehalogenation of Polychlorinated Compounds", Hazardous Waste: Detection, Control, Treatment, ed. R. Abbou, pp. 1615-1619, (1988).
Coq, et al., "Conversion Under Hydrogen of Dichlorodifluoromethane Over Bimetallic Palladium Catalysts", Applied Catalysis A: General, 101, pp. 41-50, (1993).

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