Decarbonylation of N-butyraldehyde using zeolite catalysts

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

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C07C 100

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active

045174008

ABSTRACT:
A process is provided for decarbonylating aldehydes to olefins having one less carbon atom than the aldehydes, carbon oxide and hydrogen, by passing the aldehydes over a catalyst comprising a metal selected from the group consisting of palladium, platinum, rhodium, copper, silver, gold and zinc supported on or exchanged onto a support.

REFERENCES:
patent: 3352924 (1967-11-01), Gladrow et al.
patent: 4039584 (1977-08-01), Falbe et al.
patent: 4260841 (1981-04-01), Holland et al.
Tsuji et al., JACS, 90:1, Jan. 3, 1968.

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