Debromination

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07J 700

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043258816

ABSTRACT:
A process for 9.alpha.-debromination of 9.alpha.-bromo-11.beta.-hydroxy steroids without eliminating the 11.beta.-hydroxyl group utilizing chromous chloride or chromous sulfate and thioglycolic acid.

REFERENCES:
patent: 3480622 (1969-11-01), Barton
Tetrahedron Letters 43, 3151 (1964).
J. Am. Chem. Soc. 88, 3016 (1966).
J. Am. Chem. Soc. 79, 1130 (1957).

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