Deblocking process for allyl esters with regeneratable polymer s

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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540222, 540310, 540350, C07D50104, C07D49904

Patent

active

051244489

ABSTRACT:
A regeneratable polymer-supported Pd(O) catalytic deblocking process using a regeneratable polymer-supported Pd(O) catalyst in a biphasic system deblocks various allyl-protected ester, carbonates, carbamates and cinnamyl esters.

REFERENCES:
patent: 4314942 (1982-02-01), McCombie
Clark et al., J. Am. Chem. Soc. vol. 100, pp. 7779-7781 (1978).
Jeffrey et al., J. Org. Chem., vol. 47, pp. 587-590 (1982).

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