Dealkalized sheet glass

Stock material or miscellaneous articles – Surface property or characteristic of web – sheet or block – Surface modified glass

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428432, 428428, 65 31, 65601, B32B 1700

Patent

active

050931962

ABSTRACT:
Dealkalized sheet glass having a core region which is not dealkalized, having a pre-dealkalization bulk sodium ion concentration of at least 8%, calculated as weight percent sodium oxide in the sheet glass, which pre-dealkalization bulk sodium ion concentration continues to be maintained in the core region of the sheet glass, and having a surface which is dealkalized to a depth such that a sodium ion concentration gradient exists. The sodium ion depletion is maximum at the surface, the depth at which the sodium ion concentration is 90% of the pre-dealkalization bulk sodioum ion concentration is at least twice the depth at which the sodium ion concentration is 50% of the predealkalization bulk sodium ion concentration, and the sodium ion concentration at a depth of 50 nm is not more than 50% of the pre-dealkalization bulk sodium ion concentration. A long-lasting dealkalization is achieved because of a reduced tendancy to ionic migration due to the shape of said sodium ion concentration gradient.

REFERENCES:
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patent: 3653864 (1972-04-01), Rothermel et al.
patent: 4022947 (1977-05-01), Grubb et al.
patent: 4026692 (1977-05-01), Bartholomew
patent: 4427488 (1984-01-01), Servais et al.
patent: 4518222 (1985-05-01), Borrelli
patent: 4624729 (1986-11-01), Bresciani et al.
patent: 4636439 (1987-01-01), Breininger
Patent Abstracts of Japan, vol. 6, No. 227 (R-134)[1105], 12 Nov. 1982, JP-A-57 129845, Ookura, N.
Chemical Abstracts, vol. 91, No. 16, Oct. 1979, P. 280, 127849t; JP-A-79 040816, Wakai, N.
Mochel, E. L. et al., "Strenghtening of Glass Surfaces . . . ", J. Am. Ceramic Soc., vol. 49, No. 11, 21 Nov. 1966, pp. 585-589.

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