De-emulsification of oils

Mineral oils: processes and products – Refining – Water removal

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Details

208187, 252358, 210708, C10G 3304

Patent

active

048881074

ABSTRACT:
The specification describes and claims a method for the de-emulsification of emulsions of water and crude oil which comprises treating the emulsion with an organosiloxane, a siloxane unit having a quaternary ammonium group R'N.sup.+ (R.sup.2).sub.3 X.sup.- linked to its silicon atom, R' represents a divalent hydrocarbon group linking the silicon and nitrogen atoms, each R.sup.2 represents an alkyl group having up to 20 carbon atoms or a polyoxyalkylene chain having 3 to 50 oxyalkylene groups, and X.sup.- represents a halogen ion. Examples of organosiloxanes given include those composed exclusively of the said units, and copolymers composed of these siloxane units and siloxane units according to the general formula R.sub.b (SiO.sub.4-b)/2 in which each R is a substituted or unsubstituted hydrocarbon group of up to 10 carbon atoms, and b has the value 0. 1, 2 or 3, for example those according to the average general formula

REFERENCES:
patent: 4374734 (1983-02-01), Meucombe
patent: 4457371 (1984-07-01), McCoy et al.
patent: 4501911 (1985-02-01), Koerner et al.

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