Cyclopropanecarboxylate pesticides and their preparation

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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260410, 260430, 260465D, 260544D, 260544L, 260544P, 548479, 548513, 549473, 549479, 549488, 549499, 560124, 560238, 560240, 560255, 562473, 562506, 568303, 568342, 568365, 568420, 568442, 568591, 568592, C07C 43315, C07C 5344, C07C 6914, C07C 6916, C07C 47198, C07C 4737

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active

045187975

ABSTRACT:
Compounds of the formula ##STR1## wherein R.sup.1 is an acyl group or certain optionally halo-substituted hydrocarbyl groups, and X is --CH.sub.2 CH(OCH.sub.3).sub.2, --CH.sub.2 CHO, --CH.dbd.CHOR.sup.2 in which R.sup.2 is acyl, --CHO,--C(O)Cl, --C(O)Br or --C(O)OR in which R is H, a salt-forming cation, an alkyl group or the residue of a pyrethroid alcohol are new pesticides or intermediates therefore. The compounds are prepared using a multi-step synthesis starting from the natural terpene, 3-carene.

REFERENCES:
patent: 3527769 (1970-09-01), Matsui et al.
patent: 3708528 (1973-01-01), Mukherjee et al.
patent: 4258205 (1981-03-01), Van Berkel et al.
Garbers et al., Tetrahedron Letters, 1, pp. 77-80 (1-1978).
Gopichand et al., Indian Journal of Chem., 13 (5-1975) pp. 433-436.

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