Cyclopropane derivatives and method of preparing the same

Organic compounds -- part of the class 532-570 series – Organic compounds – Pteroyl per se or having -c- – wherein x is chalcogen – bonded...

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544267, 544268, 544277, C07D47318, C07D47334, C07D47340

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active

059257563

ABSTRACT:
A cyclopropane derivative represented by formula (I): ##STR1## wherein B represents a group of a purine derivative. Another aspect of the method of preparing a cyclopropane derivative of formula (I) from this compound by replacing the hydroxyl group of the compound with a leaving group followed by reaction with a purine derivative.

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The Journal of Organic Chemistry, vol. 58, No. 14, Jul. 2, 1993, pp. 3767-3768, Kevin Burgess et al, "Synthesis of a Valuable Cyclopropyl Chiron for Preparations of 2,3-Methanoamino Acids".
The Journal of Organic Chemistry, vol. 57, No. 22, Oct. 23, 1992, pp. 5931-5936, Kevin Burgess et al, "Asymmetric Synthesis of All Four Stereoisomers of 2,3-Methanomethionine".
Tetrahedron Letters, vol. 30, No. 3, 1989, pp. 331-332, N. Oumar-Mahamat et al, "Mn (III)-Mediated Radical Lactonisation of Allylic Esters of Acetoacetic and Malonic Acids".
Helvetica Chimica Acta, vol. 72, No. 6, 1989, pp. 1301-1310, Michael C. Pirrung et al, "Synthesis and Study of Racemic, (1R,2S), and (1S,2R)-1-Amino-2-(Hydroxymethyl)Cyclopropane-Carboxylic Acid".

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