Cyclopentadienyl dicarbollide complexes of titanium, zirconium a

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 53, 526134, 526170, 502202, C07F 108

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052141730

ABSTRACT:
Novel cyclopentadienyl dicarbollide complexes of titanium, zirconiun and hafnium constitute a new class of neutral, 14-electron, d.degree., mixed-ring, bent-metallocene alkyl complexes which are useful as polymerization catalysts.

REFERENCES:
J. Am. Chem. Soc., 1989, 111, 2728-2729.
J. C. S. Chem. Commun., 1975 (20), 848-849.
Inorg. Chem., 1976, 15(11), 2872-2882.
Cationic Cp.sub.2 Zr(R)(L).sup.+ Complexes as Models for Metallocene-Based Ziegler-Natta Catalysts. Paper presented by Richard F. Jordan at the Apr. 26, 1990 meeting of the American Chemical Society in Boston, Mass.
J. Am. Chem. Soc., 1991, 113, 1455-1457, published Feb. 13, 1991.

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