Cyclopentadiene compound substituted with a hetero atom-containi

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 43, 556 53, 556 46, 556 58, 556136, 556140, 534 15, 526127, 526160, 526943, 502103, 502117, C07F 1700, C07F 700

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active

060720670

ABSTRACT:
Polysubstituted cyclopentadiene-containing compound, in which at least one substituent is has the formula --RDR'.sub.n, in which R is a linking group between the cyclopentadiene and the DR'.sub.n group, D is a hetero atom selected from group 15 or 16 of the Periodic Table of Elements or an aryl group, in which case R has at least the length of an ethylene group, R' is a hydrocarbon radical containing 1-20 carbon atoms (e.g., alkyl, aryl, aralkyl,. and the like, including straight chain, branched, cyclic, and derivatives thereof, and n is the number of R' groups bound to D (note that the R' groups may be identical or different).

REFERENCES:
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Chemical Abstracts, vol. 123, No. 13 (Sep. 1995), Abstract No. 169881.
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Krut'ko, D.P. et al., "Tetramethyl(2-methylthioethyl)cyclopentadienly Complexes of Zirconium(IV): Synthesis, . . . Solutions", Russian Chemical Bulletin, 1996, vol. 45, No. 4.
Ulrich Siemeling, "C.sub.5 Me.sub.4 (CH.sub.2).sub.3 OMe: A Tentacle-bearing Cyclopentadienyl Ligand and Its Use in Complex Chemistry", J. Chem. Soc. Commun., 1992, vol. 18, pp. 1335-1336.

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