Cycloolefin (co)polymers with a narrow molecular weight distribu

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526127, 526133, 526134, 526160, 526165, 526308, 525210, 525216, C08F 3208, C08F 3204, C08L 4500

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054224098

ABSTRACT:
Polymers of polycyclic olefins such as, for example, norbornene or tetracyclododecene, or copolymers of polycyclic olefins with cycloolefins and/or 1-olefins with a very narrow molecular weight distribution are obtained without ring opening by a polymerization in which a catalyst which is composed of an aluminoxane and of a stereorigid, chiral metallocene compound of an element of groups IVb to VIb is used, and in which the reaction is stopped at a time when the molecular weight distribution Mw/Mn of the polymer formed is <2.

REFERENCES:
patent: 4178424 (1979-12-01), Tenney et al.
patent: 4918133 (1990-04-01), Moriya et al.
patent: 5008356 (1991-04-01), Ishimaru et al.
patent: 5087677 (1992-02-01), Brekner et al.
Patent Abstracts of Japan, vol. 11, No. 60 (C-405)(2507) 24 Feb. 1987 and JP-A-61 221 206 (Mitsui Petrochemical Industries) 1 Oct. 1986.

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