Cyclohexanol/cyclohexanone mixtures produced from cyclohexane

Details Cyclohexanol/cyclohexanone mixtures produced from cyclohexane Cyclohexanol/cyclohexanone mixtures produced from cyclohexane

1988-11-14

1989-10-31

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568836, 568360, C07C 4533

Patent

active

048779032

ABSTRACT:
Mixtures containing cyclohexanol and cyclohexanone are produced by oxidizing cyclohexane with air, and then decomposing the cyclohexyl hydroperoxide in such reaction mixture, in the presence of the cyclohexane, to form cyclohexanol and cyclohexanone, such oxidation and/or decomposition being carried out in the presence of a manganese source, a Bronsted acid and a pyridine ligand.

REFERENCES:
patent: 3923895 (1975-12-01), Costantini et al.
patent: 4326084 (1982-04-01), Druliner et al.
patent: 4341967 (1982-07-01), Zelonka
patent: 4465861 (1984-08-01), Hermolin
patent: 4482746 (1984-11-01), Hermolin
patent: 4508923 (1985-04-01), Taylor et al.

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