Cyclobutabenzene monomers

Details Cyclobutabenzene monomers Cyclobutabenzene monomers

1992-07-01

1994-08-02

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Isocyanate esters

562488, 562855, 564427, 564428, 568327, 568738, C07C20512

Patent

active

053347528

ABSTRACT:
Novel difunctionalized cyclobutabenzene monomers of the general formula: ##STR1## wherein Z can be hydrogens or a cyclobutane ting; and X and Y are carbox amino, alcohol, isocyanate, acid halide, or bis-acyl fluoride groups. In a particularly preferred embodiment, the cyclobutabenzene derivative is 1,2-dihydrocyclobutabenzene-3,6-carboxylic acid. The difunctionalized cyclobutabenzene monomer can form part of a polymer backbone chain, but has an additional functionality, the butane ring, which can be easily opened to produce strong, covalent bond crosslinking between polymer chains. The crosslinking can be induced simply by heating the polymer to a temperature in excess of 300.degree. C.

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Watabe et al, Chem. Lett, pp. 1791-1794 (1984).
Iyoda et al, Chem. Lett, pp. 2113-2116 (1986).

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