Cyclic process for producing methane in a tubular reactor with e

Gas: heating and illuminating – Processes – Fuel mixtures

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585733, C10K 304

Patent

active

045839948

ABSTRACT:
Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

REFERENCES:
patent: 4242103 (1980-12-01), Rabo et al.
patent: 4351646 (1982-09-01), Frost et al.
Hougen et al., "Chemical Process Principles", Part three, pp. 1031-1034, John Wiley & Sons, 1947.

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