Cyclic process for oxidation of calcium sulfide

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

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423555, C01F 1110, C01F 1108

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054339391

ABSTRACT:
A cyclic process of subjecting calcium sulfide particles to alternating oxidizing and reducing conditions. The impenetrable shell of calcium sulfate which forms during the oxidation phase of the cycle is destroyed by the subsequent reducing phase. By repeating the cycle many times the particles are converted completely into calcium oxide at a reasonable temperature of about 1000.degree. C. The process can be carried out in a fluidized bed reactor either by maintaining both oxidizing and reducing zones within the same fluidized bed or by varying the gas phase throughout the fluidized bed in a periodic manner.

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Article entitled "Sulfation of Partially Sulfided Calcium-Based Sorbents" by J. Abbasian, A. Rehmat and D. D. Banerjee, Ind. Eng. Chem. Res..
Article entitled "Cyclic Operation of Fluidized Bed Reactor for Decomposing Calcium Sulfate", Chemical Engineering Communications, 109, 155-166 (1991) no month.

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