Cyanine dye activating group with improved coupling selectivity

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

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544277, 544317, 546 23, 546 24, 548113, 548547, 548548, 548549, 548579, 548565, 548453, 549473, C07F 909, C07F 9141, C07D207408, C07D48704

Patent

active

060020032

ABSTRACT:
Activating groups for cyanine dyes used to label chain terminators in nucleotide sequencing, based on N-hydroxyphthalimide, are disclosed. From these activating groups, activated dyes of the present Invention are prepared which react with the derivitized nucleotide chain terminators to give a labeled chain terminator of the present Invention. The activating groups of the present Invention allow the dye-chain terminator reaction to occur at a much higher yield and with much greater selectivity for the mono-substituted product, compared with the prior art.

REFERENCES:
Evangelista et al, Characterization of Fluorescent Nucleotide Triphosphates . . . , Analytical Biochemistry, 235, 89-97, Dec. 1996.

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