Chemistry: analytical and immunological testing – Nitrogen containing – Cyanide or isocyanide
Reexamination Certificate
2004-09-16
2010-06-08
Soderquist, Arlen (Department: 1797)
Chemistry: analytical and immunological testing
Nitrogen containing
Cyanide or isocyanide
C252S301160, C252S301220, C436S166000, C436S172000, C564S008000, C568S001000
Reexamination Certificate
active
07732215
ABSTRACT:
The present invention relates to a cyanide detection method using fluorescence and cyanide sensitive boronic acid containing fluorophores, wherein a change in a measured fluorescent property correlates to the concentration of the cyanide compound in a biological or environmental test sample.
REFERENCES:
patent: 3432269 (1969-03-01), Kramer et al.
patent: 5116759 (1992-05-01), Klainer et al.
patent: 5503770 (1996-04-01), James et al.
patent: 6462179 (2002-10-01), Stolowitz et al.
patent: 6682938 (2004-01-01), Satcher et al.
patent: 6916660 (2005-07-01), Wang et al.
patent: 7095502 (2006-08-01), Lakowicz et al.
patent: 2002/0031447 (2002-03-01), Brinz et al.
patent: 2003/0228682 (2003-12-01), Lakowicz et al.
patent: 2004/0038419 (2004-02-01), Weiner et al.
patent: 2004/0087842 (2004-05-01), Lakowicz et al.
patent: 2004/0121478 (2004-06-01), Brinz et al.
patent: 2007/0274922 (2007-11-01), Wang et al.
patent: WO 2004/024191 (2004-03-01), None
S. I. Baskin and T. G. Brewer, In Medical Aspects of Chemical and Biological Warfare, Eds. F. Sidell, E. T Takafuji and D. R. Franz, TMM publications, Washington, 1997, Chapter 10, p. 271-286.
F. J. Baud, P. Barriot, and V. Toffis (1991). Elevated blood cyanide concentrations in victims of smoke-inhalation.N. Engl. J. Med., 325(25) 1761-1766.
Z. Gryczynski, I. Gryczynski and J. R. Lakowicz, Fluorescence Sensing Methods,Methods in Enzymology, 360 (2002) 44-75.
G. J. Kavarnos, Fundamentals of Photoinduced Electron Transfer, VCH, New York, 1993, chapter 4, pp. 185-234.
J. S. Lang, D. Mullin, C. Fenyvesi, R. Rosenberg and J. Barnes (1986). Is the “protector of lions” losing his touch? (Hafez Assad)US News&World Report, Nov. 10, 1986 p. 28.
Medical expert reports use of chemical weapons in Iran-Iraq war,UN Chronicle 22(May 1985) 24-26.
A. Ishii, H. Seno, K. Watanabe-Suzuki, O. Suzuki and T Kumazawa (1998). Determination of cyanide in whole blood by capillary gas chromatography with cryogenic oven trapping.Anal. Chem., 70(22) 4873-4876.
F. Moriya and Y. Hashimoto (2001). Potential for error when assessing blood cyanide concentrations in fire victims.J. Forensic Sci., 46(6) 1421-1425.
C. J. Clark, D. Campbell and W. H. Reid (1981). Blood carboxyhemoglobin and cyanide levels in fire survivors.Lancet, 1(8234) 1332-1335.
D. Keilin (1929). Cytochrome and Respiratory Enzymes. Proc. R. Soc Lond.B. Biol. Sci., 104 206-251.
C. Giuriati, S. Cavalli, A. Gorni, D. Badocco and P. Pastore (2004). Ion chromatographic determination of sulfide and cyanide in real matrices by using pulsed amperometric detection on a silver electrode.J. Chromato. A, 1023(1) 105-112.
M. T. Fernandez-Arguelles, J. M. C. Costa-Fernandez, R Pereiro and A. Sanz-Medel (2003). Room temperature phosphorimetric determination of cyanide based on triplet state energy transfer.Anal. Chim. Acta., 491(1) 27-35.
J. D. Favero and M. Tubino (2003). Semi-quantitative “spot-test” of cyanide.Anal. Sci., 19(8) 1139-1143.
J. V. Ros-Lis, R. Martinez-Manez and J. Soto (2002). A selective chromogenic reagent for cyanide determination.Chem. Commun., 19 2248-2249.
K Cho, Y. S Jang, M. S. Gong, K Kim and S. W. Joo (2002). Determination of cyanide species in silver and gold plating solutions by Raman spectroscopy.Appl. Spectrosc., 56(9) 1147-1151.
G. Drochioiu (2002). Highly selective and sensitive reaction of cyanide with 2,2-dihydroxy-1,3-indanedione.Anal. Bioanal. Chem., 372(5-6) 744-747.
C. Hughes, F. Lehner, L. Dirikolu, D. Harkins, J. Boyles, K McDowell, T. Tobin, J. Crutchfield, M. Sebastian, L. Harrison and S. I. Baskin (2003). A simple and highly sensitive spectrophotometric method for the determination of cyanide in equine blood.Toxicol. Mech. Methods, 13(2) 129-138.
A. Ipatov, M. Ivanov, S. Makarychev-Mikhailov, V. Kolodnikov, A. Legin and Y. Vlasov (2002). Determination of cyanide using flow-injection multisensor system.Talanta, 58(6) 1071-1076.
M. Hoshino, K Nagashima, M. Kamaya and N. Nakano (2003. Spectrophotometric determination of cyanide ion in waste water using copper(II) and N,N-diethyl-p-phenylenediamine.Bunseki Kagaku, 52(6) 481-484, abstract and title only.
G. Drochioiu (2002). Fast and highly selective determination of cyanide with 2,2-dihydroxy-1,3-indanedione.Talanta, 56(6) 1163-1165.
A. Tracqui, J. S. Raul, A. Geraut, L. Berthelon and B. Ludes (2002). Determination of blood cyanide by HPLC-MS.J. Anal. Toxicol., 26(3) 144-148.
B. Vallejo-Pecharroman and M.D. L. de Castro (2002). Determination of cyanide by a pervaporation-UV photodissociation-potentiometric detection approach.Analyst, 127(2) 267-270.
W. R. Premasiri, R. H. Clarke, S. Londhe and M. E. Womble (2001). Determination of cyanide in waste water by low-resolution surface enhanced Raman spectroscopy on sol-gel substrates.J. Raman Spectrsc., 32(11) 919-922.
D. E. Barnes, P. J. Wright, S. M. Graham and E. A. Jones-Watson (2000). Techniques for the determination of cyanide in a process environment: A review.Geostandards Newsletter—The Journal of Geostandards and Geoanalysis, 24(2) 183-195.
D. L. Recalde-Ruiz, E. Andres-Garcia and M. E. Daiz-Garcia (2000). Fluorimetric flow injection and flow-through sensing systems for cyanide control in waste water.Analyst, 125(11) 2100-2105.
T. Mansfeldt and H. Biernath (2000). Determination of total cyanide in soils by micro-distillation.Anal. Chim Acta., 406(2) 283-288.
E. Nakamura and M. Yagi (2000). Spectrophotometric determination of cyanide with isonicotinic acid sodium barbiturate.Bunseki Kagaku, 49(1) 55-58, title and abstract.
E. Miralles, R. Compano, M. Granados and M. D. Prat (2000). Determination of metal-cyanide complexes by ion-interaction chromatography with fluorimetric detection.Anal. Chim. Act., 403(1-2) 197-204.
C. D. Geddes (2001). Optical halide sensing using fluorescence quenching: theory, simulations and applications—a review.Meas. Sci. Technol., 12(9) R53-R88.
R. Badugu, J. R. Lakowicz and C. D. Geddes,Anal. Biochem. R. Badugu, J.R. Lakowicz and C.D. Geddes (2004). The non-invasive continuous monitoring of physiological glucose using a novel monosaccharide-sensing contact lens.Anal Chem., 76(3), 610-618.
N. Dicesare and J. R. Lakowicz (2001). Spectral properties of fluorophores combining the boronic acid group with electron donor or withdrawing groups. Implication in the development of fluorescence probes for saccharides.J. Phys. Chem. A, 105(28) 6834-6840.
N. Dicesare and J. R. Lakowicz (2002). Charge transfer fluorescent probes using boronic acids for monosaccharide signaling.J. Biomedical Optics, 7(4) 538-545.
N. Dicesare and J. R. Lakowicz (2001). Wavelength-ratiometric probes for saccharides based on donor-acceptor diphenylpolyenes.J. Photochem. Photobiol. A: Chem., 143 39-47.
N. DiCesare, D. P. Adhikari, J. J. Heynekamp, M. D. Heagy and J. R. Lakowicz (2002). Spectroscopic and photophysical characterization of fluorescent chemosensors for monosaccharides based on N-phenylboronic acid derivatives of 1,8-naphthalimide.J. Fluorescence, 12(2) 147-154.
R. Badugu, J. R Lakowicz and C. D. Geddes (2005). Cyanide-sensitive fluorescent probes.Dyes&Pigments, 64(1) 49-55.
R. Badugu, J. R. Lakowicz and C. D. Geddes (2003). A glucose sensing contact lens: a non-invasive technique for continuous physiological glucose monitoring.J. Fluorescence, 13(5) 371-374.
N. Dicesare and J.R. Lakowicz (2002). Chalcone-analogue fluorescent probes for saccharides signaling using the boronic acid group.Tetrahedron Lett., 43(14) 2615-2618.
N. Dicesare and J.R. Lakowicz (2001). A new highly fluorescent probe for monosaccharides based on a donor-acceptor diphenyloxazole.Chem Commun., 19 2022-2023.
N. Dicesare and J.R. Lakowicz (2001). New color chemosensors for monosaccharides based on Azo dyes.Org. Lett., 3(24) 3891-3893.
Z. Filipovic-Kovaceic, M. Miksaj and D. Salamon (2002). Cyanide determination in fruit brandies by an amperometric biosensor with immobilisedSaccharomyces cerevisiae. Eur. Food Res. Technol., 215(4), 347-352.
N. Dicesare and J.R. Lakowicz (2001). Evaluation of two synthetic glucose probes for fluorescence-lifetime-based sensing.A
Badugu Ramachandram
Geddes Chris D.
Lakowicz Joseph R.
Fuierer Marianne
Moore & Van Allen PLLC
Soderquist Arlen
University of Maryland Biotechnology Institute
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