Cyanide recovery

Chemistry of inorganic compounds – Nitrogen or compound thereof – Carbon containing

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423367, 4236585, 423 24, 423 29, 210683, 210684, 210904, 75105, C01C 308, B01J 4104, C02F 142, C22B 300

Patent

active

042671590

ABSTRACT:
Spent aqueous liquor containing cyanide, as from ore treatment, is passed through a bed of suitable anion-exchange resin to segregate the cyanide, which is subsequently recovered in regeneration of the resin by weak alkaline solution. Both the eluted cyanide and the alkaline regenerant are recycled, if desired, for further ore treatment. A most important benefit of such procedure is nearly complete elimination of cyanide as a component of the treatment effluent. Free cyanide may be separated from complexed cyanides when present by using weak alkaline regenerant to elute the free cyanide from the resin and stronger alkaline regenerant to elute the complexed cyanides.

REFERENCES:
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patent: 2839389 (1958-06-01), Kember
patent: 2965441 (1960-12-01), Welton
patent: 3001868 (1961-09-01), Aveston
patent: 3656893 (1972-04-01), Sloan
patent: 3788983 (1974-01-01), Fries
patent: 3869383 (1975-03-01), Shimamura
patent: 3984314 (1976-10-01), Fries
patent: 4115260 (1978-09-01), Avery
Goldblatt "Recovery of Cyanide from Waste Cyanide Solutions by Ion Exchange", Industrial and Engineering Chemistry (3/59) pp. 241-246. _
Yagashita et al., "Regeneration of Anion Exchange Resins Containing Cyanide from Waste Water" in Chemical Abstracts, vol. 79 (1973) No. 96,643s. _

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