Curing preceramic polymers by exposure to nitrogen dioxide

Plastic and nonmetallic article shaping or treating: processes – Carbonizing to form article – Filaments

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264 56, 264 65, 264 83, 26421114, 26421116, 26421117, D01F 910, D01F 1104

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050512153

ABSTRACT:
A rapid method of infusibilizing (curing) preceramic polymers comprising treatment said polymers with gaseous nitrogen dioxide. The infusibilized polymers may be pyrolyzed to temperatures in excess of about 800.degree. C. to yield ceramic materials with low oxygen content and, thus, good thermal stability. The methods are especially useful for the production of ceramic fibers and, more specifically, to the on-line production of ceramic fibers.

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