Curable polyene-polythiol hydantoin compositions

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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20415915, 20415918, 20415923, 20415924, 260 47CB, 260 775AP, 260 775BB, 260 795C, 260 797, 2603095, 427 54, 428425, 428419, 428457, C08F 246, C08F 818

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039842975

ABSTRACT:
A curable composition comprising compatible polyene and polythiol in which both the components are derived from a hydantoin glycol. The polyene is typically a reaction product of N,N'-bis(2-hydroxyethyl) dimethylhydantoin, a diisocyanate and an unsaturated alcohol, e.g., allyl alcohol. The polythiol is typically a reaction product of N,N'-bis(2-hydroxyethyl) dimethylhydantoin and a mercapto carboxylic acid, e.g., .beta.-mercaptopropionic acid. Upon exposure to a free radical generator, e.g., actinic radiation, this polyene-polythiol composition cures to solid, insoluble, chemically resistant, cross-linked polythioether products.

REFERENCES:
patent: 3697395 (1972-10-01), Kehr et al.
patent: 3839354 (1974-10-01), Habermeier et al.
patent: 3945982 (1976-03-01), Morgan

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