Curable compositions and process

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 18S, 260825, 528 14, 528 15, 528 16, 528 17, 528 18, 528 19, 528 34, C08G 7704, C08L 4304

Patent

active

041001290

ABSTRACT:
Self-bonding, low modulus, one-package room temperature vulcanizing silicone compositions, curable in the presence of moisture, comprise (a) a silanol chain-stopped polydiorganopolysiloxane; (b) a cross-linking silane; and (c) a silanol reactive organometallic ester compound of a metal, the compound having radicals attached to the metal atom, at least one of the radicals being a substituted or unsubstituted hydrocarbonoxy radical, attachment being through M--O--C linkages, where M is the metal, and any remaining valences of M are satisfied by other organo radicals attached to M through such linkages, or an --OH, --O-- or M--O--M linkage, the weight ratio of components (c) to (b) always being at least 0.5 to 1. Such compositions have unusually high adhesion to a variety of difficulty bondable substrates.

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