Curable base-resistant fluoroelastomers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C524S544000, C524S545000, C524S546000, C524S547000, C524S551000, C524S570000, C524S800000, C526S247000, C526S249000, C526S250000, C526S253000, C526S255000, C526S291000, C526S292900, C526S294000, C526S296000, C526S332000, C526S348800, C526S348000

Reexamination Certificate

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07576164

ABSTRACT:
Compositions of fluoroelastomers containing copolymerized units of tetrafluoroethylene, propylene, a first cure site selected from the group consisting of i) trifluoroethylene, ii) 3,3,3-trifluoropropene-1, iii) 1,2,3,3,3-pentafluoropropylene, iv) 1,1,3,3,3-pentafluoropropylene, and v) 2,3,3,3-tetrafluoropropene, and a second cure site selected from the group consisting of i) copolymerized units of a brominated cure site monomer, ii) copolymerized units of an iodinated cure site monomer, iii) copolymerized units of a chlorinated cure site monomer, iv) brominated endgroups, v) iodinated endgroups and vi) a combination of any of i)-v) are readily curable with polyhydroxy curing systems. The resulting cured articles have a combination of excellent resistance to alkaline fluids, superior tensile properties and compression set resistance, and excellent adhesion to metal substrates. Optionally, the fluoroelastomers may be dual cured by both a polyhydroxy system and an organic peroxide system.

REFERENCES:
patent: 4214060 (1980-07-01), Apotheker et al.
patent: 4882390 (1989-11-01), Kolb
patent: 4912171 (1990-03-01), Grootaert et al.
patent: 4957975 (1990-09-01), Carlson et al.
patent: 5648429 (1997-07-01), Chiodini et al.
patent: 6703450 (2004-03-01), Bauerle et al.
patent: 2003/0065132 (2003-04-01), Bauerle et al.
patent: 2003/0225189 (2003-12-01), Fuller

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