Cucurbiturils and method for binding gases and volatiles...

Gas separation: processes – Liquid contacting – And separation of solid from contact liquid

Reexamination Certificate

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C095S226000, C095S230000, C095S232000, C095S233000, C095S237000, C095S238000, C095S239000

Reexamination Certificate

active

06869466

ABSTRACT:
In accordance with the invention, there is provided a method of binding a gas or volatile compound in a cucurbituril, by contacting the gas or volatile compound with the cucurbituril to form a cucurbituril-gas/volatile complex. There is also provided a method of separating a gas or volatile compound from a mixture of compounds wherein the mixture is contacted with a cucurbituril and whereby at least some of the gas or volatile compound is bound to the cucurbituril to form a cucurbituril complex, followed by the release of at least some of the bound gas or volatile compound from that complex. The present invention is thus advantageous in that it allows use of cucurbiturils in binding gases and volatile compounds for storage, safety, delivery or other uses, such as the trapping of an unpleasant or toxic gas or volatile compound.

REFERENCES:
patent: 6365734 (2002-04-01), Kim et al.
patent: 20030212268 (2003-11-01), Kim et al.
patent: 10126394 (2002-12-01), None
patent: 1 094 065 (2001-04-01), None
patent: 1210966 (2002-06-01), None
patent: 11217557 (1999-08-01), None
Grant, Julius (Editor), “Hackh's Chemical Dictionary” Fourth Edition (McGraw-Hill Book Company, New York, 1972), p. 717, “volatile” & “volatilization” & “volatilize.”*
Lewis, Richard J., Sr. (Revised by), “Hawley's Condensed Chemical Dictionary” Fourteenth Edition (John Wiley & Sons, Inc., New York, 2001), p. 1169, “volatility.”*
JPO abstract for JP11-21557-A, Taketsuji (Aug. 10, 1999).*
USPTO obtained translation of EP 1210966 A1.*
Cintas, P. “Cucurbituril: Supramolecular Perspectives for an Old Ligand” “Journal of Inclusion Phenomena and Molecular Recognition in Chemistry” 17:205-220, 1994.*
Abstract for WO 02/096553 A2.*
Derwent abstract ACC-NO.: 2002601193, for EP 1210966A1 (Jun. 5, 2002) Blum et al.*
Mock, et al. “Host-Guest Binding Capacity of Cucurbituril”, J. Org. Chem., 1983, 48 (20), 3618-3619.*
Flinn, et al. “Decamethylcucurbit[5]uril”, Angew. Chem. Int. Ed. Engl., 1992,31,(11), 1475-1477.*
Kim et al. “New Cucurbituril Homologues: Syntheses, Isolation, Characterization, and X-ray Crystal Structures of Cucurbit[n]uril (n=5, 7, and 8)” J. Am. Chem. Soc., 2000, 122, 540-541.*
USPTO obtained translation of DE 4001139 (Jan. 25, 1990), Buschmann, et al.*
Dantz et al. “Complexation of Volatile Organic Molecules from the Gas Phase with Cucurbituril and β-Cyclodextrin”, Supramolecular Chemistry, vol. 9, pp. 79-83, 1998.
Kellensberger et al., “Encapsulation of N2, O2, Methannol, or Acetonitrile by Decamethylcucurbit[5]uril . . . ” J. Am. Chem. Soc. 2001, 123, pp. 11316-11317, web release date Oct. 20, 2001.
Haouaj et al., “NMR Study of the reversible complexation of xenon by cucurbituril”, J. Chem. Soc. Perkin Trans 2, 2001,pp. 804-807.
Haouaj et al., “NMR Investigation of the complexation of neutral guests by cucurbituril”, J. Chem. Soc. Perkins Trans. 2, 2001, pp. 2104-2107.
Jeon et al., “Molecular Container Assembly Capable of Controlling Binding and Release of Its Guest Molecules . . . ”, J. Am. Chem. Soc. 1996, 118, p. 9790.
Miyahara et al., “Molecular Molecular Sieves: Lid-Free Decamethylcucurbit[5]uril Absorbs and Desorbs Gases Selectively” Angew. Chem. Int. Ed. 2002, 41, No. 16, pp. 3020-3023.

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