Crystallized IM-8 solid of metallophosphate type and process...

Chemistry of inorganic compounds – Phosphorus or compound thereof – Oxygen containing

Reexamination Certificate

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C423S306000, C423SDIG030

Reexamination Certificate

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06998101

ABSTRACT:
A crystallized solid of metallophosphate type, referred to by the designation IM-8 can be partially substituted by an element X and optionally by an element Y. The metallophosphate is of a chemical composition, expressed on an anhydrous basis is defined by the formula Rs(GgPpXxYy)O2in which G represents one or more trivalent elements, R represents one or more organic compounds, X represents one or more divalent elements, and Y represents one or more tetravalent elements, and in which s≦0.2, g≦0.5, p≦0.5, x≦0.4 and y≦0.3 with g+p+x+y=1. The crystallized solid is useful as an adsorbent.

REFERENCES:
patent: 4310440 (1982-01-01), Wilson et al.
patent: 4440871 (1984-04-01), Lok et al.
Chippindale A M et al.; “CoGaPO-5: Synthesis and crystal structure of (C6N2H14)2'Co4Ga5P9036!, a microporpous cobalt-gallium phosphate with a novel framework topology” Zeolites, Elsevier Science Publishing, U.S. vol. 18, No. 2, Feb. 1, 1997 pp. 176-181.
Bond A D et al.: “Synthesis and characterization of transition-metal-substituted gallium phosphates with the laumonite structure” Zeolites, Elsevier Science Publishing, U.S. vol. 19, No. 5-6, Nov. 12, 1997, pp. 326-333.
Reinert P. et al.: “Synthesis, characterization and structure determination of a new fluorogallophosphate (Mu-3) prepared in the presence of ethylene glycol as main solvent” Microporous and Mesoporous Materials, Elsevier Science Publishing, New York, US, vol. 22, No. 1-3, Jun. 17, 1998, pp. 43-55.
Chippindale A M et al.: “Heteroatom-substituted microporous gallium phosphates” Microporous and Mesoporous Materials, Elsevier Science Publsihing, New York, US vol. 21, No. 4-6, May 1, 1998 pp. 271-279.

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