Crystalline maltosyl glucoside, and its production and use

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

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5361231, 53612313, 536127, 435 72, 435 96, 435 97, 435 98, 435 99, 435101, 435 74, C12P 1944, C07H 306

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059123303

ABSTRACT:
Novel crystalline maltosyl glucoside is obtained by crystallizing maltosyl glucoside from a maltosyl glucoside solution, prepared by exposing either an aqueous solution containing trehalose and an .alpha.-glucosyl saccharide or an aqueous solution containing a reducing partial starch hydrolysate to the action of a saccharide-transferring enzyme. The crystalline maltosyl glucoside has non-hygroscopicity, non-reducibility, superior solubility, less fermentability, and other properties of stabilizing oligopeptides and biologically-substances as well as preventing retrogradation of amylaceous substances. These features render it very useful in various compositions including foods, beverages, cosmetics, pharmaceuticals and shaped bodies.

REFERENCES:
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Hendrix et al, Carbohydr. Res. 253:329-334 (1994).
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Shinkiti Koto et al, .alpha.-D-Glucosylation by 6-O-Acetyl-2,3,4-tri-O-benzyl-D-glucopyranose Using Trimethylsilyl Triflate and Pyridine. Synthesis of .alpha.-Maltosyl and .alpha.-Isomaltosyl .alpha.-D-Glucosides, Bulletin of Chemical Society of Japan, vol. 59, pp. 411-414, Feb. 1986.
Hans Peter Wessel et al, 67, .alpha.-D-Glycosyl-Substituted .alpha.,.alpha.-D-Trehaloses with (1-->4)-Linkage: Syntheses and NMR Investigations, Helvetica Chimica Acta, vol. 74, pp. 682-695, 1991.
Klaus Bock et al, Carbon-13 Nuclear Magnetic Resonance Data for Oligosaccharides, Advances in Carbohydrate Chemistry and Biochemistry, vol. 42, pp. 193-225, 1984.
Frank H. Stodola, The Preparation, Properties and Structure of the Disaccharide Leucrose, Journal of the American Chemical Society, vol. 78, pp. 2514-2518, Jun. 5, 1956.

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