Crosslinked bead polymers and their preparation

Stock material or miscellaneous articles – Coated or structually defined flake – particle – cell – strand,... – Particulate matter

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526279, 526301, 526311, 526314, 526332, 5253265, C08F 800, C08F24600, C08F23008

Patent

active

050453955

ABSTRACT:
Crosslinked bead polymers having an average particle diameter in the range of from 0.5-10 .mu.m and a narrow particle size distribution can be prepared by polymerization of vinyl monomers and silane monomer units which contain a hydrolysable group, the polymerization being carried out in a non-aqueous, polar medium using a free-radical former as the initiator in the presence of a polymer which is soluble in this medium and acts as a dispersant, and furthermore in the presence of a low molecular weight surfactant, and the resulting polymer is then crosslinked by the action of an aqueous acid or base.

REFERENCES:
patent: 3706697 (1972-12-01), Backderf
patent: 4048422 (1977-09-01), Sackmann
patent: 4147688 (1979-04-01), Makhlouf
patent: 4287299 (1981-09-01), Himmelmann
patent: 4524131 (1985-06-01), Himmelmann
patent: 4614708 (1986-09-01), Timmermann
patent: 4861818 (1989-08-01), Timmermann
Houben-Weyl, Methods of Organic Chemistry, vol. E20/I, p. 227.
Ullmann, Encyclopedia of Industrial Chemistry, vol. 19, p. 132.

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