Crosslinked and crosslinkable hollow fiber membrane and...

Gas separation: apparatus – Apparatus for selective diffusion of gases – Hollow fiber or cylinder

Reexamination Certificate

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C096S014000, C055S524000, C055SDIG005

Reexamination Certificate

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06932859

ABSTRACT:
A composition of and a method of making high performance hollow fiber membranes is described. The membranes have a high resistance to plasticization by use of a predetermined amount of crosslinking. The preferred polymer material for the membrane is a polyimide polymer comprising covalently bonded ester crosslinks. The resultant hollow fiber membrane exhibits a high permeability of CO2in combination with a high CO2/CH4selectivity. Another embodiment provides a method of making the hollow fiber membrane from a monesterified polymer followed by final crosslinking after hollow fiber formation.

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