Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Reexamination Certificate
2003-04-07
2009-10-06
Andres, Janet L. (Department: 1625)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
C526S336000, C556S021000, C556S022000, C556S136000, C502S152000, C502S155000
Reexamination Certificate
active
07598330
ABSTRACT:
The invention pertains to the use of Group 8 transition metal alkylidene complexes as catalysts for olefin cross-metathesis reactions. In particular, ruthenium and osmium alkylidene complexes substituted with an N-heterocyclic carbene ligand and at least one electron donor ligand in the form of a heterocyclic group are used to catalyze cross-metathesis reactions to provide a olefin products that are directly substituted with an electron-withdrawing group.
REFERENCES:
patent: 5312940 (1994-05-01), Grubbs et al.
patent: 5342909 (1994-08-01), Grubbs et al.
patent: 5831108 (1998-11-01), Grubbs et al.
patent: 5969170 (1999-10-01), Grubbs et al.
patent: 6111121 (2000-08-01), Grubbs et al.
patent: 6211391 (2001-04-01), Grubbs et al.
patent: 6306988 (2001-10-01), Grubbs et al.
patent: 2003/0100776 (2003-05-01), Grubbs et al.
patent: WO 03/011455 (2003-02-01), None
Collamn Principles and applications of Organotransition Metal Chemistry pp. 509 (1980).
Sanford et al. (2001) J. Am Chem. Soc., 123:6543-6554,.
Brümmer et al. (1997) “Olefin Cross-Metathesis with Monosubstituted Olefins,”Chem. Eur. J. 3:441- 446.
Chatterjee et al. (2000), “Synthesis of Functionalized Olefins by Cross and Ring-Closing Metatheses,”J. Am. Chem. Soc. 122(15):3783-3784.
Crowe et al. (1995) “Acrylonitrile Cross-Metathesis: Coaxing Olefin Metathesis Reactivity from a Reluctant Substrate,”J. Am. Chem. Soc. 117:5162-5163.
Goldberg et al. (2002), “A One-Pot Cross-Metathesis/Allylboration Reaction: A Three-Component Coupling for the Synthesis of Functionalized Homoallylic Alcohols,”Angew. Chem. Int. Ed. 41(5):807-810.
Itoh et al. (2000) “Synthesis of Bis- and Oligo-gem-difluorocyclopropanes Using the Olefin Metathesis Reaction,”Org. Lett. 2:1431.
Toste et al. (2002), “Functional Group Diversity by Ruthenium-Catalyzed Olefin Cross-Metathesis,”Pure Appl. Chem. 74(1):7-10.
Trnka et al. (2001), “The Development of L2X2Ru=CHR Olefin Metathesis Catalysts: An Organometallic Success Story,”Accounts of Chemical Research34(1):18-29.
Wilhelm et al. (1997), “Reactivity of Ru(H)(H2)C1(PCy3)2with Propargyl and Vinyl Chlorides: New Methodology to Give Metathesis-Active Ruthenium Carbenes,”Organometallics16(18):3867-3869.
Blanco et al., (1999) “New results on the functionalization of terminal alkenes by cross-metathesis reactions,”Synlett, 5:557-558.
Chatterjee et al., (1999) “Synthesis of trisubstituted alkenes via olefin cross-metathesis,”Org. Lett. 1(11):1751-1753.
Love et al, (2002) “A practical and highly active ruthenium-based catalyst that effects the cross metathesis of acrylonitrile,”Angew. Chem. Int. Ed. 41(21):4035-4037.
Sanford et al., “Mechanism and activity of ruthenium olefin metathesis catalysts,” J. Am: Chem. Soc., 2001, 123:6543-6554.
Grubbs Robert H.
Love Jennifer A.
Morgan John P,.
Trnka Tina M.
Andres Janet L.
California Institute of Technology
Covington Raymond
LandOfFree
Cross-metathesis of olefins directly substituted with an... does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Cross-metathesis of olefins directly substituted with an..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Cross-metathesis of olefins directly substituted with an... will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-4095261