Cross-linked polybenzimidazole membrane for gas separation

Gas separation: processes – Selective diffusion of gases – Selective diffusion of gases through substantially solid...

Reexamination Certificate

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C095S047000, C095S050000, C095S051000, C095S055000, C096S013000, C096S014000

Reexamination Certificate

active

06997971

ABSTRACT:
A cross-linked, supported polybenzimidazole membrane for gas separation is prepared by reacting polybenzimidazole (PBI) with the sulfone-containing crosslinking agent 3,4-dichloro-tetrahydro-thiophene-1,1-dioxide. The cross-linked reaction product exhibits enhanced gas permeability to hydrogen, carbon dioxide, nitrogen, and methane as compared to the unmodified analog, without significant loss of selectivity, at temperatures from about 20 degrees Celsius to about 400 degrees Celsius.

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