Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...
Reexamination Certificate
2000-10-23
2002-02-12
Moore, Margaret G. (Department: 1712)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Processes of preparing a desired or intentional composition...
C524S710000, C524S111000, C524S148000, C524S135000, C524S151000, C528S015000, C528S031000
Reexamination Certificate
active
06346562
ABSTRACT:
The present invention relates to crosslinkable mixtures, a process for preparing them and their use.
When using addition-crosslinking silicone rubber systems, a generally encountered problem is that once the reactive mixture has been prepared it has a finite curing rate even at room temperature. This is a particularly noticeable problem when the machines are not running for a relatively long time as a result of technical malfunctions or other causes. In such a case, the reactive silicone rubber mixture present in the machines can crosslink even at room temperature, which results in very costly cleaning work before the machines are restarted.
For this reason, there has for a long time been a market demand for addition-crosslinking silicone rubber systems which, ideally, do not cure at all at room temperature and have a very high reaction rate under processing conditions.
To achieve this aim, inhibitors are customarily added to the rubber systems. One group of inhibitors comprises organophosphorus compounds. Thus, for example, DE-A-3 635 236 describes the use of cyclometallated platinum-phosphite complexes for increasing the shelf life at room temperature. The catalyst inhibitor complexes described there increase the pot life at room temperature, but have the disadvantage that they are complicated to prepare, which is associated with additional costs in production. EP-A-662 490 describes organophosphorus compounds as inhibitors in addition-crosslinking silicone systems. However, the aliphatic and aromatic phosphines described there have the disadvantage that they cause a significant slowing of the reaction rate under processing conditions (T=120 to 170° C.). DE-P 19532316.5 describes addition-crosslinkable mixtures which contain an organophosphorus compound and an inhibitor in addition to a hydrosilylation catalyst. However, the use of a two-component system as described there is complicated. Mixtures which have complete inhibition at room temperature and no influence on the reaction rate under curing conditions with an additive are not previously known.
It is therefore an object of the invention to provide suitable mixtures which, even in fast, addition-crosslinking silicone systems, reduce the activity of the catalyst at room temperature without prolonging the curing times under reaction conditions.
In addition, the mixture should have a make-up which is as simple as possible, i.e. be composed of as few components as possible.
It has now been found that the problems in addition-crosslinking polysiloxane mixtures can be solved by these mixtures containing Pt compounds or elemental Pt or another substance which catalyses hydrosilylation and at least one phosphorus compound of the type specified in more detail below which bears a bulky substituent.
The invention accordingly provides crosslinkable mixtures comprising as components
a) at least one polysiloxane which has at least two olefinically or acetylenically unsaturated multiple bonds,
b) at least one polyhydrogensiloxane which has at least two hydrogen atoms bound directly to the silicon,
c) at least one substance which catalyses the hydrosilylation,
d) at least one compound of the formula (I)
R
1
n
P(OR)
3−n
(I)
where
n=an integer in the range 0-3,
R and R
1
are, independently of one another, compounds selected from the following group
where
R″=
—H,
—CR′″
3
,
—SiR′″
3
,
—Hal,
—OR′″ and/or
(CR
4
2
)
m
—P(OR
1
)
1
R
2−1
where
l=0-2
m=1 to 10 and
R
4
=H, —CR′″
3
,
—SiR′″
3
, —Hal, —OR′″ and/or SiR′″
3
,
where at least one radical R″ has to be different from H and when n=0, at least one of the radicals R″ is SiR′″
3
, and
R′″=saturated or unsaturated C
1
-C
30
-alkyl, aryl, C
7
-C
31
-arylalkyl and/or C
7
-C
31
-alkylaryl radicals which may bear functional groups such as carboxylic acid derivatives
or the reaction product of the components c) and d) and
e) if desired, further auxiliaries.
Component a) for the purposes of the invention is preferably a cyclic, linear or branched polysiloxane built up of units of the general formula (II)
(R
3
)
3
(R
4
)
b
SiO
(4−a−b)/2
(II).
In this formula, R
3
is a C
2
-C
8
-alkenyl radical, e.g. vinyl, allyl, 1-butenyl, 1-hexenyl, etc. The alkenyl radicals can be bound to silicon atoms within the chain or at the end of the chain. R
4
is a monovalent, saturated hydrocarbon radical having up to 10 carbon atoms selected from the group consisting of substituted and unsubstituted alkyl, aryl and arylalkyl radicals. Examples of monovalent radicals R
4
are methyl, ethyl, propyl, isopropyl, butyl, octyl etc., cyclobutyl, cyclopentyl, cyclohexyl etc., phenyl, tolyl, xylyl, naphthyl, etc., benzyl, phenylethyl, phenylpropyl. The integers a and b are as follows: 0≦a≦3 and 0 ≦b≦3 and 0≦a+b≦4. Preferably, a is 0 or 1. In the radicals R
4
of the present invention, some or all hydrogen atoms can be replaced by fluorine and/or chlorine, bromine or iodine atoms or cyano groups. This means that R
4
can also be, for example, a chloromethyl, trifluoropropyl, chlorophenyl, dibromophenyl, cyanoethyl or cyanopropyl radical.
The molecular weight of the polysiloxane is preferably 100-600,000.
Using the nomenclature with which those skilled in the art are familiar
M (CH
3
)
3
SiO
1/2
D (CH
3
)
2
SiO
2/2
T (CH
3
)SiO
3/2
M
Vi
(CH
2
=CH) (CH
3
)
2
SiO
1/2
═D
Vi
(CH
2
=CH) (CH
3
)SiO
2/2
,
the following examples of the component a) may be given:
M
2
D
100
3
Vi
M
2
Vi
D
160
M
Vi MD
100
D
3
Vi
T
5
D
550
M
7
Vi
T
3
D
500
M
2
Vi
M
2
T
6
D
300
D
Vi
M
4
Vi
M
4
M
2
Vi
D
1000
M
2
Vi
D
1000
D
50
Vi
and
M
2
D
2000
D
5
Vi
.
The mole fraction of unsaturated radicals of the R
3
type can be chosen at will.
In the component a), the mole fraction of unsaturated radicals of the R
3
type is preferably between 10
−3
and 10 mmol per gram. The expression “between” always includes, both here and in the following, the lower and upper values indicated.
For the purposes of the present invention, the component b) is a polysiloxane which is built up of units of the general formula (III)
H
c
(R
4
)
d
SiO
(4−c−d)/2
(III)
where R
4
has been defined above and R
4
may also be as defined for R
3
. The stoichiometric indices c and d are integers as follows: 0≦d≦3 and 0≦c≦2 and 0≦c+d ≦4. Preferably, 0≦c≦1.
The molecular weight of the component b) is preferably 100-12,000.
Using the nomenclature with which those skilled in the art are familiar
Q SiO
4/2
M
H
H(CH
3
)
2
SiO
1/2
D
H
H(CH
3
)SiO
2/2
,
the following examples of the component b) may be given:
M
2
H
D
10
,
M
2
D
10
D
10
H
,
M
2
H
D
20
D
10
H
,
M
2
Vi
D
11
H
,
M
2
D
3
Vi
D
6
H
, and
QM
1.3−16
H
D
0.1
,
(M, D, M
Vi
and D
Vi
as defined for component a)).
The mole fraction of hydrogen atoms bound directly to a silicon atom in the component b) can be selected at will.
In the component b), the mole fraction of hydrogen atoms bound directly to a silicon atom is preferably between 0.01 and 17 mmol, particularly preferably between 0.1 and 17 mmol and very particularly preferably between 1 and 17 mmol, per gram of component b).
In the total mixture described, the components a) and b) should preferably be present in such a mixing ratio that the molar ratio of hydrogen atoms bound directly to a silicon atom (SiH) in the component b) to the unsaturated radicals (Si-vinyl) in the component a) is between 0.05 and 20, particularly preferably between 0.5 and 10 and very particularly preferably between 1 and 5.
For the purposes of the invention, component c) preferably comprises the elements platinum, rhodium, indium, nickel, ruthenium and/or palladium in elemental form on a support material or in the form of their compounds. Preference is given to platinum compounds or platinum complexes, for example H
2
PtCl
6
, platinum-olefin compl
Haselhorst Rolf
Karch Ralf
Zimmermann Klaus
LandOfFree
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