Covalently fixed porphyrin polymer having porphyrin metal...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From aluminum- or heavy metal-containing reactant

Reexamination Certificate

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C540S145000, C514S185000, C514S410000, C534S015000, C424S009362, C424S009610

Reexamination Certificate

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07094866

ABSTRACT:
A covalently linked linear porphyrin polymer represented by formula (1):whereinR represents an alkyl group or (wherein a, b and d independently represent H, an alkyl group or aryl group);X represents —O—, —S—, >NR101(wherein R101represents H or an alkyl group), —CH2— or a single bond;Y represents ═O, ═S, or 2H;m represents an integer of 0 to 4;n represents an integer of 0 to 6;Z represents a five- or six-membered, nitrogen-containing, coordinating hetero aromatic ring group;M represents an ion of metal selected from typical metals and transition metals;Q1represents a single bond or a linear, divalent linking group; andp1represents an integer of 2 or more.

REFERENCES:
patent: 6429310 (2002-08-01), Kobuke et al.
patent: 6602998 (2003-08-01), Kobuke et al.
Kofuya et al, Mercapto substituted imidazolylporphyrin metal complex monomers, their polymers, and their preparation, 2001, Jpn. Kokai Tokkyo Koho., Chem Abstract 135: 257635.
Kofuya et al, Manufacture of polyporphyrins having imidazolylporphyrin metal complex unit, 2001, Jpn. Kokai Tokkyo Koho, Chem Abstract 135: 153257.□□.
Stibrany et al, Two modes—a structural and spectroscopic comparison, 1996, Journal of the American Chemical Society, Chem Abstract 124: 330619.
Ken-ichi Sugiura, et al. “AMandala-PatternedBandanna-Shaped Porphyrin Oligomer, C1244H1350N84Ni20O88, Having a Unique Size and Geometry” Chemistry Letters No. 11, pp. 1193-1194, Nov. 5, 1999.
Naoki Aratani, et al. “Extremely Long, Discretemeso-meso- Coupled Porphyrin Arrays” Angewandte Chemie International Edition vol. 39, No. 8, Apr. 17, 2000, pp. 1458-1462.
Akihiko Tsuda, et al. “Fully Conjugated Porphyrin Tapes With Electronic Absorption Bands That Reach Into Infrared” Science, vol. 293, Jul. 6, 2001, pp. 79-82.
Yoshiaki Kobuke, et al. “Covalent Fastening of Coordination-Organized Supramolecule” Abstract of XIIth International Symposium on Supramolecular Chemistry at Eilat, Israel, Oct. 6-11, 2002, 3 pages.

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