Coupling process

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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585452, 585453, C07C 264

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active

049508318

ABSTRACT:
An alkene is coupled with an aromatic hydrocarbon having an active hydrogen on a saturated alpha-carbon in the presence of an unsupported alkali metal as a catalyst under high shear agitation conditions. In preferred embodiments of the invention, the alkene is an alkene of 2-20 carbons, such as ethene or propene; the active hydrogen-containing aromatic hydrocarbon is an alkyl-benzene, such as toluene; the alkali metal is potassium or a potassium alloy; and the high shear agitation conditions are attained by operating a turbine-type impeller at a tip speed of at least about 5 m/sec.

REFERENCES:
patent: 3006976 (1961-10-01), Shaw et al.
patent: 3449455 (1969-06-01), Napolitano et al.
patent: 3470265 (1969-09-01), Sprow
patent: 4179580 (1979-12-01), Cobb
patent: 4356337 (1982-10-01), Pez et al.

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