Coupling of polymers made by cationic polymerization

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525314, 525316, C08F 1010, C08F29700, C08F29300

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active

056908610

ABSTRACT:
A method for coupling a cationic polymer includes forming a reaction mixture of a cationic polymer and a bis(diphenylethylene). The reaction mixture is exposed to a temperature which causes the bis(diphenylethylene) to react with the cationic polymer, thereby coupling to cationic polymer. In another embodiment, the method includes forming a reaction mixture of an oxo-acid and a isopropenyl polyisobutylene. The reaction mixture is exposed to a temperature below about -30.degree. C., whereby the oxo-acid reacts with isopropenyl polyisobutylene, thereby coupling the polymer.

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patent: 5451647 (1995-09-01), Faust
patent: 5458796 (1995-10-01), Storey et al.
Kennedy et al., "Correlation between Cationic Model and Polymerization Reactions of Olefins," Institute of Polymer Science, The University of Akron, pp. 1-48 (1973).
Tung et al. "Dilithium Anionic Initiators Based on Double 1,1-Diphenylethylene Compounds," Macromolecules, 11(3):616-617 (1978).
Quirk et al., "Anionic Synthesis of Hetero Three-Armed Star Polymers Via 1,1-Diphenylethylene-Functionalized Macromonomers," Institute of Polymer Science, The University of Akron, pp. 578-579.
Hasegawa et al., "Selective Dimerization of Disobutylene by Oxo Acids: Synthesis of Isobutylene Tetramer," Journal of Applied Polymer Science, 27:171-181 (1982).

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