Coupling of aryl and heteroaryl mono chlorides

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By ring formation from nonring moiety – e.g. – aromatization,...

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252459, C07C 126

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active

042634660

ABSTRACT:
Aryl and heteroaryl mono chlorides are coupled in an aprotic solvent under an inert atmosphere by a catalyst mixture of a nickel compound and a ligand in the presence of a reducing metal.

REFERENCES:
patent: 3414629 (1968-12-01), McCall et al.
patent: 3641175 (1972-02-01), Wilke et al.
patent: 3661882 (1972-05-01), Hawkins et al.
patent: 3736264 (1973-05-01), Chauvin
patent: 3856868 (1974-12-01), Fahey
patent: 3859327 (1975-01-01), Wells
patent: 4000211 (1976-12-01), Smith et al.
Michio Zembayashi et al., Tetrahedron Letters, No. 47, pp. 4089-4092, 1977.
Takakazu Yamamoto, Bull. Chem. Soc. Japan 51 (7), pp. 2091-2097, 1978.

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