Coupled resinous diene copolymer with good integral hinge flex l

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C08F29704

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active

040910539

ABSTRACT:
A conjugated diene/monovinyl-substituted aromatic compound resinous copolymer such as a styrene/butadiene block copolymer is produced using two additions of the monovinyl-substituted aromatic component and initiator in a manner such that the product has 71 to 81 wt. percent monovinyl-substituted aromatic component and has a ratio based on the number average molecular weight of monovinyl-substituted aromatic component blocks in first and second polymer chains thus produced prior to coupling within the range of 3 to 7. The final product resulting from coupling such polymers has long integral hinge flex life and high hardness. This is accomplished by using no more than 5 millimoles of initiator per mole of monomer in the second addition.

REFERENCES:
patent: 3639517 (1972-02-01), Kitchen

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