Drug – bio-affecting and body treating compositions – Anti-perspirants or perspiration deodorants
Reexamination Certificate
2001-10-17
2003-07-08
Dodson, Shelley A. (Department: 1616)
Drug, bio-affecting and body treating compositions
Anti-perspirants or perspiration deodorants
C424S066000, C424S068000, C424S400000, C424S401000
Reexamination Certificate
active
06589515
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to compositions in which a liquid phase is thickened or structured, including cosmetic compositions for application to human skin. Significant forms of the invention are concerned with antiperspirant compositions for application to human skin, especially the axilla. However, the invention can also be applied to other forms of cosmetic composition and to compositions used for other purposes.
BACKGROUND OF THE INVENTION AND SUMMARY OF PRIOR ART
Many compositions have been proposed for various uses in which a liquid phase is thickened or structured. These include a wide variety of cosmetic compositions for application to human skin, which make use of a thickened or structured liquid carrier to deliver colour or some other active material to the surface of the skin. A significant example of such cosmetic compositions are antiperspirant compositions which are widely used in order to enable their users to avoid or minimise wet patches on their skin, especially in axillary regions.
Antiperspirant formulations have been provided with a range of different product forms. One of these is a so-called “stick” which is usually a bar of an apparently firm solid material held within a dispensing container and which retains its structural integrity and shape whilst being applied. When a portion of the stick is drawn across the skin surface a film of the stick composition is transferred to the skin surface. Although the stick has the appearance of a solid article capable of retaining its own shape for a period of time, the material usually has a structured liquid phase so that a film of the composition is readily transferred from the stick to another surface upon contact.
Another possibility is that a stick is a softer solid composition accommodated in a dispensing container which in use extrudes the composition through one or more apertures.
Antiperspirant sticks can be divided into three categories. Suspension sticks contain a particulate antiperspirant active material suspended in a structured carrier liquid phase. Emulsion sticks normally have a hydrophilic phase containing the antiperspirant active in solution, this phase forming an emulsion with a second, more hydrophobic, liquid phase. The continuous phase of the emulsion is structured. Solution sticks typically hive the antiperspirant active dissolved in a structured liquid phase which may be a mixture of water and a water-miscible organic solvent. This classification into suspension, emulsion and solution types can be applied to both firm and soft solid compositions.
Other types of cosmetic composition can also be provided in the form of a stick and again the stick may be a structured solution, emulsion or suspension. Examples of cosmetic compositions which are, or can be, marketed in a stick form are lipsticks, lip salves and eyebrow pencils.
There is substantial literature on the structuring or thickening of cosmetic compositions.
Conventionally, many sticks have been structured using naturally-occurring or synthetic waxy materials. Examples of these include those fatty alcohols which are solid at room temperature, such as stearyl alcohol, and hydrocarbon waxes or silicone waxes. Such materials are widely available, and by suitable selection of the materials themselves and their concentrations in the formulation, it is possible to obtain either a soft solid or a firm solid. Examples of these sticks are described in an article in Cosmetics and Toiletries, 1990, Vol 105, P75-78 and in U.S. Pat. Nos. 5,169,626 and 4,725,432. However, fatty alcohol or wax structured sticks tend to leave visible white deposits on application to human skin, and the deposits can also transfer onto clothing when it comes into contact with the skin and the wearer can, for example, find white marks at the armhole of the sleeveless garment.
Some alternative structurants have been proposed. The term “gellant” is often employed instead of “structurant”. Where the resulting product is liquid of increased viscosity rather than a solid or gel, the term “thickener” can also be used. For example, the use of dibenzylidene sorbitol (DBS) or derivatives thereof has been proposed as gellant in a number of publications such as EP-A-512770, WO 92/19222, U.S. Pat. Nos. 4,954,333, 4,822,602 and 4,725,430. Formulations containing such gellants can suffer from a number of disadvantages, including instability in the presence of acidic antiperspirants, and comparatively high processing temperatures needed in the production of sticks.
A combination of an N-acylaminoacid amide and 12-hydroxy stearic acid to gel a non-aqueous formulation is described in, for example, WO 93/23008 and U.S. Pat. No. 5,429,816. However, high processing temperatures are needed to dissolve the gellants and prevent premature gelling. When applied to skin the formulation can be difficult to wash off, but reformulation to overcome that problem can be made impossible by the need for a high processing temperature.
The use of 12-hydroxy stearic acid without N-acylamino acid amide as a secondary gellant has been disclosed in some documents such as Japanese application 05/228915 and U.S. Pat. No. 5,744,130.
In WO 97/11678 to Helene Curtis, Inc, there is described the use of starch hydrolysate esters as a gellant for making soft gels for antiperspirant compositions. There is discussion of fatty acid esters of dextrin as one such material. Partially esterified sucrose is another possibility: preferably it is only esterified on two or three of its hydroxy groups. A further paragraph suggests that other mono, di or oligosaccharides could be esterified and used in similar fashion. Maltose is named but no further details are given.
Antiperspirant emulsion sticks without any material identified as a structurant have been disclosed in U.S. Pat. Nos. 4,673,570, 4,948,578 and 5,587,153.
Cosmetic compositions other than antiperspirants which take the form of structured liquids have been disclosed, for example in U.S. Pat. No. 3,969,087, which disclosed the use of N-acylamino acids and derivatives thereof as gelling agents, U.S. Pat. No. 5,486,566 which utilised 12-hydroxy stearic acid.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide thickened or structured compositions, for example cosmetics compositions especially but not exclusively antiperspirant compositions, in which a liquid carrier material is thickened or structured using a structuring agent which is different from those mentioned above. A further object of the invention is to provide a structurant which can have superior properties to at least some of the structurants which have been used previously.
A further object of at least some forms of the invention is to provide compositions which exhibit low visible deposits. Certain particularly preferred forms of the invention have the objective of providing compositions which have a measure of clarity, i.e. are translucent or even transparent.
A still further object of one aspect of the present invention is to provide novel thickeners or structurants. According to a first aspect of the present invention there is provided a composition of matter having a continuous phase which comprises water-immiscible liquid carrier and a structurant therein which is wholly esterified or partially esterified maltose in which at least half the available hydroxyl groups have been esterified to bear acyl groups containing at least four carbon atoms and which has more &bgr;-anomer than &agr;-anomer. Such a compound is represented by the formulae:
which is the &bgr;-anomer and optionally
which is the &agr;-anomer;
wherein each Z is independently hydrogen or an acyl group of the formula:
where R denotes a hydrocarbyl group containing from 8 to 31 carbon atoms, with the proviso that not more than half of the Z groups are hydrogen. The amount of &bgr;-anomer exceeds the amount of &agr;-anomer. Such compositions may be suitable for cosmetic use.
The fully or partially esterified maltose serves as a structuring agent or thickener for the water-immiscible liquid
Franklin Kevin Ronald
Lasbistes Nicolas
Webb Nicholas
White Michael Stephen
Dodson Shelley A.
Stein Kevin J.
Unilever Home & Personal Care USA , division of Conopco, Inc.
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