Corrosion inhibiting pigment composition and method

Compositions: coating or plastic – Materials or ingredients – Pigment – filler – or aggregate compositions – e.g. – stone,...

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106 1442, 106 1441, 106 1405, 106 1444, 106419, 106425, 106429, 423143, 423144, 423147, 423368, 423369, 423DIG8, C04B 1436

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054877792

ABSTRACT:
A method of preparing a (Me)bis-hydrogen cyanamide composition with enhanced corrosion preventive activity, wherein Me is a divalent metal selected from the group consisting of nickel and cobalt or mixtures thereof. The method includes precipitating Ni(OH).sub.2 or Co(OH).sub.2 or mixtures thereof, in situ in a liquid reaction medium, containing a soluble cobalt or nickel salt and sodium hydroxide and a stoichiometric excess of H.sub.2 NCN and immediately reacting the resultant precipitate with H.sub.2 NCN. Precipitation of coprecipitated pigment compositions including the aforementioned derivatives and zinc cyanamide is also disclosed.

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Advanced Inorganic Chemistry, Cotton, F. A. et al., Interscience, 1966, pp. 605, 865.
Chem. Abs. 69:100291 of "Thermochemical Study of some metal cyanamides. I. Enthalpies of formation." in Bull. Soc. Chim. Fr. (1968), (6), 2357, Bernard, M.
Chem. Abs. 69:99876, ibid, ". . . II. Thermochemical study of hydrolysis kinetics for cyanamide in aqueous media." Bull. Soc. Chim. Fr. (1968), (6), 2359-61, Bernard, M.
"Chimie Mineral--Sur des cyanamides de nickel et de cobalt", Maurice A. Bernard and Annie Chemin, Jan. 17, 1966. (English translation also attached).

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