Correlation of weighted effect of different ions and surfactant

Wells – Processes – With indicating – testing – measuring or locating

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166273, E21B 4322

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active

041228952

ABSTRACT:
In the recovery of oil from a formation with an aqueous surfactant solution containing an anionic surfactant such as a petroleum sulfonate, a cosurfactant such as tertiary butyl alcohol, and an electrolyte, a specific surfactant system which is suitable for the given formation, is selected by: (1) analyzing the formation brine and determining the total effective NA.sup.+ concentration, on the basis that each part Ca.sup.++ is equivalent to about 14 parts Na.sup.+ and each part Mg.sup.++ is equivalent to about 16 parts Na.sup.+ ; (2) comparing this total effective Na.sup.+ concentration with previously prepared phasevolume diagrams of surfactant systems partitioning into separate phases as a function of electrolyte concentration; and (3) adjusting the electrolyte concentration, hydrophobic content of the surfactant, or solubility of the alcohol to give a particularly effective system for recovering oil.

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