Core-shell fluoropolymer dispersions

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

Reexamination Certificate

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C524S546000

Reexamination Certificate

active

06841594

ABSTRACT:
A dispersion of non-melt-processible fluoropolymer particles having an SSG of less than about 2.225 in aqueous medium. The fluoropolymer particles comprise a core of high molecular weight polytetrafluoroethylene having an average melt creep viscosity greater than about 1.5×1010Pa·s and a shell of lower molecular weight polytetrafluoroethylene or modified polytetrafluoroethylene. The shell has an average melt creep viscosity greater than about 9×109Pa·s and comprises about 5 to about 30% by weight of the particles. The fluoropolymer in the dispersion of the invention is fibrillating.

REFERENCES:
patent: 3037953 (1962-06-01), Marks et al.
patent: 3142665 (1964-07-01), Cardinal et al.
patent: 3819594 (1974-06-01), Holmes et al.
patent: 4837267 (1989-06-01), Malhotra
patent: 5324785 (1994-06-01), Noda et al.
patent: 5506281 (1996-04-01), Muhlbauer
patent: 5707763 (1998-01-01), Shimizu et al.
patent: 0322877 (1989-07-01), None
patent: 0 758 010 (1997-02-01), None
Sperati & Starkwather, Fortschr. Hochpolym-Forsch.BD. 2, S.465-495 (1961).

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